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Keto-enol/enolate equilibria in the N-acetylamino-p-methylacetophenone system. Effect of a beta-nitrogen substituent

Autor: ‖ A. C. O'Donoghue, H. Heckroth, Yvonne Chiang, B. Hellrung, A. G. Griesbeck, J. Wirz, and J. P. Richard, Q. Meng, A. J. Kresge

Publikováno v: Journal of the American Chemical Society. 123(37)

The cis-enol of N-acetylamino-p-methylacetophenone was generated flash photolytically and its rates of ketonization in aqueous HClO(4) and NaOH solutions as well as in HCO(2)H, CH(3)CO(2)H, H(2)PO(4)(-), (CH(2)OH)(3)CNH(3)(+), and NH(4)(+) buffers we

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7970595add6dc89bbc7d26c5e5e8957a
https://pubmed.ncbi.nlm.nih.gov/11552805

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