Zobrazeno 1 - 10
of 13
pro vyhledávání: '"B. G. Zykov"'
Autor:
A. S. Yavorskii, B. G. Zykov, V. I. Khvostenko, O. G. Khvostenko, S. A. Andronati, I. A. Prokopenko
Publikováno v:
Russian Chemical Bulletin. 42:1517-1521
Photoelectron (PE) spectra of 20 biologically active molecules of 1,4-benzodiazepine derivatives have been measured. The spectra in the range of low ionization energies (IE) were interpreted by comparison of MNDO quantum-chemical calculation data wit
Autor:
Z. N. Saraeva, O. A. Ponomarev, Abdrakhmanov Ildus B, Tolstikov Genrikh A, N. G. Nigmatullin, B. G. Zykov
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 40:552-556
Using the LCAO MO method in the MNDO approximation, we have compared the concerted [3, 3]-sigmatropic and stepwise mechanisms for the acid-catalyzed Claisen amino rearrangement. The latter is preferred.
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:1603-1610
We have obtained for the first time the photoelectron spectra (PES) of 20 diamagnetic and paramagnetic derivatives of imidazole. On the basis of calculations in the MNDO approximation, analysis of the vibrational structure, and comparisons in a serie
Publikováno v:
Scopus-Elsevier
By means of negative ion mass spectrometry (resonant electron capture spectra) the interaction of electrons (0–15 eV) with molecules of phthalide and its substitutes has been studied. These molecules model monomer links of polymers in which phenome
Autor:
V. A. Dokichev, Oleg M. Nefedov, Ravil I. Khusnutdinov, Tolstikov Genrikh A, Usein M. Dzhemilev, S. R. Rafikov, B. G. Zykov, A. Sh. Sultanov
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 31:795-799
1. Dimerization and codimerization of 2- and 7-substituted norbornadienes in the presence of low-valent iron complexes gives new mono- and 5(6), 11-disubstituted exo-trans-exopentacyclo [8.2.1.14,702,90.3,8]tetradeca-5,11-dienes in high yields. 2. Ac
Autor:
B. G. Zykov, Nail L. Asfandiarov
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 32:2069-2072
1. The photoelectron spectra of seven methyl-substituted 1,3-dioxanes have been recorded and identified. 2. Empirical parameters have been found which characterize the magnitude of the inductive effect and the hyperconjugation between theσC-C bonds
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 30:2252-2255
Conformational analysis and determination of the most probable conformations of the linear acetals have been carried out by combining photoelectron spectroscopy with mass spectrometry of the negative ions resulting from dissociative electron capture.
Autor:
B. G. Zykov
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 35:2035-2039
1. A scheme for the evaluation of the pπ-dπ conjugation based on the comparison of data from photoelectron spectroscopy and the results of quantum-chemical calculations in the framework of Koopman's theorem has been proposed, and evaluations of the
Autor:
V. I. Khvostenko, O. G. Khvostenko, Nail L. Asfandiarov, S. A. Andronati, V. A. Mazunov, B. G. Zykov, T. N. Voronina, G. S. Lomakii, L. N. Yakubovskaya, A. S. Yavorskii
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 36:1175-1180
1. E- and Z-conformations of 1,2-dehydro-3H-1,4-benzodiazepin-2-ones are realized in the gas phase and in solution as the result of the inversion of the seven-membered ring. 2. The Z-conformers possess weak physiological activities or none at all. 3.
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 30:1006-1013
1. We observe a substantial reduction in the p-π conjugation of the S atom with the aromatic system on going from phenyl to pentafluorophenyl derivatives of divalent sulfur. 2. The first ionization potential of pentafluorophenyl derivatives of dival