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Autor: Owen W. Webster, R. D. Farlee, B. E. Smart, F. P. Gentry

Publikováno v: Makromolekulare Chemie. Macromolecular Symposia. :477-482

In a search for new types of polymer architecture, we have examined systems where one couples rigid-rod monomers with multifunctional tie-point monomers. High surface area (400–1000 m2/g) polymeric carbinols result from reaction of 4,4′-dilithiob

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::bd9be8ad2ce14cdd4bc9168ba3f14621
https://doi.org/10.1002/masy.19920540135

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Silicon-Mediated Synthesis of Poly(Fluorovinyl Ethers) and Poly(Perfluoroalkenes)

Autor: B. E. Smart, M. J. Nappa, W. B. Farnham

Publikováno v: Progress in Pacific Polymer Science 2 ISBN: 9783642776380

Under the influence of anionic catalysts, silyl ethers react with perfluorinated olefins to produce exceptionally high yields of partially fluorinated vinyl ethers. The number of vinyl fluorines substituted can be controlled for a wide variety of flu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::ee2e7e5822465b7daeb000ebbb3e252a
https://doi.org/10.1007/978-3-642-77636-6_7

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Non-planar structures of the pentafluoroallyl and 1,1-difluoroallyl anions

Autor: Tadamichi Fukunaga, B. E. Smart, David A. Dixon

Publikováno v: Journal of Physical Organic Chemistry. 1:153-160

The structures of the allyl anion (1) and two fluoro-substituted derivatives, perfluoro (2) and 1,1-difluoro (3) have been calculated by ab inito molecular orbital theory. Geometries were gradient optimized, and force fields and an MP-2 correlation c

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2e3bb559ec14208679ade9732acfc8ef
https://doi.org/10.1002/poc.610010305

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