Zobrazeno 1 - 10 of 29 pro vyhledávání: '"B. E. Holmes"'
2
Detection of HF using infrared degenerate four-wave mixing
Autor: R. L. Vander Wal, David J. Rakestraw, B. E. Holmes, Roger L. Farrow, J. B. Jeffries, Paul M. Danehy
Publikováno v: Chemical Physics Letters. 191:251-258
Resonant degenerate four-wave mixing is demonstrated for the detection of HF using both the (1-0) and (3-0) vibrational transitions near 4000 and 11500 cm −1 , respectively. The use of rovibrational transitions in DFWM potentially allows the sensit
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b9abfe74c4e8f6f93f879a4410584544
https://doi.org/10.1016/0009-2614(92)85296-m
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3
Unimolecular rate constants for HX or DX elimination (X = F, Cl) from chemically activated CF3CH2CH2Cl, C2H5CH2Cl, and C2D5CH2Cl: threshold energies for HF and HCl elimination
Autor: J D, Ferguson, N L, Johnson, P M, Kekenes-Huskey, W C, Everett, G L, Heard, D W, Setser, B E, Holmes
Publikováno v: The journal of physical chemistry. A. 109(20)
Vibrationally activated CF(3)CH(2)CH(2)Cl molecules were prepared with 94 kcal mol(-1) of vibrational energy by the combination of CF(3)CH(2) and CH(2)Cl radicals and with 101 kcal mol(-1) of energy by the combination of CF(3) and CH(2)CH(2)Cl radica
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::d3717f10ff0b7ea1131f9250c29c6342
https://pubmed.ncbi.nlm.nih.gov/16833790
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4
Infrared degenerate four-wave mixing
Autor: D. J. Rakestraw, R. L. Vander Wal, B. E. Holmes, R. L. Farrow, J. B. Jeffries
Publikováno v: Optical Society of America Annual Meeting.
In degenerate four-wave mixing, three input beams of identical frequency interact with a nonlinear medium to generate a fourth coherent signal beam. The efficiency is resonant with an atomic or molecular transition. The coherent nature of the signal
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8f9455713f6bd5379f50b32f8f200473
https://doi.org/10.1364/oam.1991.tue2
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5
Akademický článek
Unimolecular Reactions of Vibrationally Excited CF2ClCHFCH3and CF2ClCHFCD3:  Evidence for the 1,2-FCl Interchange Pathway.
Autor: M. O. Burgin, J. G. Simmons Jr., G. L. Heard, D. W. Setser, B. E. Holmes
Publikováno v: Journal of Physical Chemistry A; Mar2007, Vol. 111 Issue 12, p2283-2292, 10p
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7
Energy disposal in the three-centered elimination of df from 1,1,2-trifluoroethane-1-d1
Autor: B. E. Holmes, D. W. Setser, G. O. Pritchard
Publikováno v: International Journal of Chemical Kinetics. 8:215-234
The chemical activation data for three- and four-centered hydrogen fluoride elimination from CH2FCDF2 have been analyzed to assign the energy released to the olefin fragment in the three-centered process and to estimate the threshold energies for eli
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::dea55c1a286f72d610c2ad406808f078
https://doi.org/10.1002/kin.550080206
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8
Generation of ground electronic state haloalkyl radicals in the gas phase
Autor: D. J. Rakestraw, E. E. King, S. D. Paisley, B. E. Holmes
Publikováno v: International Journal of Chemical Kinetics. 18:639-649
Preparation de radicaux halogenoalkyles gazeux par photolyse d'iodohalogenoalcanes dans des reacteurs en pyrexe contenant des halogenures de Hg(I). La scission de la liaison C-I, donne un halogenure de Hg(II) et un radical qui reagit sur une surface
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7d9702258e27afa08d2e63a0dc5a863b
https://doi.org/10.1002/1097-4601(198606)18:6<639::aid-kin550180604>3.0.co
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