Zobrazeno 1 - 4
of 4
pro vyhledávání: '"Béatrice M. Chabot"'
Autor:
Derek H. R. Barton, Béatrice M. Chabot
Publikováno v:
Tetrahedron. 53:511-520
The selective functionalization of alkane was achieved in a good yield, by a simple FeIICl2 salt and bis(trimethylsilyl) peroxide in pyridine. Unlike the FeII-H2O2 system, no extra ligand was needed. The presence of a carbon radical from the FeII-FeI
Autor:
Béatrice M. Chabot, Derek H. R. Barton
Publikováno v:
Tetrahedron. 52:10287-10300
Utilization of the FeII-H2O2 system in the presence of diphenyl diselenide, phenylselenol, diphenyl disulfide and thiophenol converts saturated hydrocarbons into the corresponding alkyl phenyl selenide or alkyl phenyl sulfide. Starting with FeIII-H2O
Autor:
Roy U. Rojas Wahl, Valérie N. Le Gloahec, Bin Hu, Nathalie C. Delanghe, Derek H. R. Barton, Béatrice M. Chabot
Publikováno v:
Tetrahedron Letters. 36:7007-7010
The substitution of saturated hydrocarbons by the anions nitrite, thiocyanate, azide and chloride, using H2O2 and TBHP as oxidants has been shown to depend upon the FeII-FeIV manifold and to involve radical chemistry. As soon as the FeII has been oxi
Autor:
Béatrice M. Chabot, Derek H. R. Barton, Warinthorn Chavasiri, Dennis K. Taylor, Stéphane D. Bévière
Publikováno v:
Tetrahedron Letters. 35:4681-4684
New methodology for the oxidation of alcohols to ketones in good yield utilizing catalytic amounts of Fe III salts and TBHP as the oxidant is highlighted. Competition between alcohol and hydrocarbon oxidation has been clearly demonstrated. The “nor