Výsledky vyhledávání - "Ayla Buenaventura"

The Role of H-Bonding in Non-Concerted Proton-Coupled Electron Transfer: Explaining the Voltammetry of Phenylenediamines in the Presence of Weak Bases in Acetonitrile

Autor: Laurie A Clare, Tammy Dung Pham, Lily Rafou, Ayla Buenaventura, Veronika Mikhaylova, Diane K Smith

Publikováno v: ECS Meeting Abstracts. :1861-1861

The kinetics of many proton-coupled electron transfer (PCET) reactions cannot be adequately described by step-wise proton and electron transfer. Concerted electron-proton transfer (CPET) is another possibility, but examples exist where step-wise mech

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::72aa275ffee74c7d22389a0ee2f0a155
https://doi.org/10.1149/ma2019-01/36/1861

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The Role of Hydrogen Bonding in Proton-Coupled Electron Transfer. It Does Not Have to be Concerted Pcet: The Case of Phenylenediamines and Pyridines in Acetonitrile

Autor: Diane K. Smith, Laurie A. Clare, Tammy Dung Pham, Lily Rafou, Ayla Buenaventura, Colin Arthurs

Publikováno v: ECS Meeting Abstracts. :2033-2033

Proton transfer often accompanies electron transfer in organic redox couples due to the large changes in acidity or basicity that result from oxidation or reduction. Classically, the overall reaction is thought to occur in two separate steps, either

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f01f50412f09be2d786633bf680f729f
https://doi.org/10.1149/ma2018-01/34/2033

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Evaluating the Roles of Proton Transfer and H-Bonding in the Electron Transfer Reactions of Organic Redox Couples in Non-Aqueous Solvents: Oxidation of Phenylenediamines in the Presence of Pyridine Bases in Acetonitrile

Autor: Tammy Dung Pham, Laurie A. Clare, Lily Rafou, Ayla Buenaventura, Colin Arthurs, Diane K. Smith

Publikováno v: ECS Meeting Abstracts. :2583-2583

Oxidation or reduction of organic redox couples typically leads to large changes in acidity or basicity, with the result that proton transfer often accompanies electron transfer, particularly in aqueous solution. In less polar organic solvents, H-bon

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::304526a877a00db24120bbd601590b81
https://doi.org/10.1149/ma2018-01/44/2583

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