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pro vyhledávání: '"Avigdor Persky"'
Autor:
Avigdor Persky
Publikováno v:
Chemical Physics Letters. 439:3-7
The rate constant of the F + NH 3 reaction has been determined in the temperature range 276–327 K, using a discharge-flow mass spectrometric technique. A relative rate method has been employed, using the F + CH 4 reaction as a reference reaction. T
The temperature dependence of the kinetic isotope effect in the reaction of F atoms with CH4 and CD4
Autor:
Avigdor Persky
Publikováno v:
Chemical Physics Letters. 430:251-254
The kinetic isotope effect k F + CH 4 / k F + CD 4 has been determined by reacting F atoms with mixtures of CH 4 and CD 4 , using a discharge-flow-mass spectrometric technique. Experiments were carried out at four temperatures in the temperature rang
Autor:
Avigdor Persky
Publikováno v:
Chemical Physics Letters. 401:455-458
The rate constants for the two channels of the reaction of F atoms with HD, kF + HD and kF + DH, have been determined in the temperature range 193–300 K. The sum of rate constants kF + HD + kF + DH was determined by a competitive method and a disch
Autor:
Avigdor Persky, Haya Kornweitz
Publikováno v:
The Journal of Physical Chemistry A. 108:8599-8604
Quantum mechanical cross sections for the two channels of the F + HD reaction, calculated and published by Zhang et al. (J. Chem. Phys. 2000, 112, 9802) employing the potential energy surface of Stark and Werner (J. Chem. Phys. 1996, 104, 6515) were
Autor:
Avigdor Persky, Haya Kornweitz
Publikováno v:
The Journal of Physical Chemistry A. 108:140-145
LEPS potential energy surfaces were constructed for the reactions F + HCl, F + HBr, and F + HI so as to reproduce the available experimental kinetic data and data concerning the energy distribution among products as well as possible. Calculations wer
Autor:
Avigdor Persky
Publikováno v:
Chemical Physics Letters. 380:286-291
The ratio of rate constants kF+DBr/kF+H2 has been determined by a discharge-flow-mass spectrometric technique and was found to exhibit a linear Arrhenius temperature dependence in the range 210–298 K. Based on the linear dependence reported for kF+
Autor:
Avigdor Persky
Publikováno v:
Chemical Physics Letters. 376:181-187
The temperature dependence of the rate constants for the reactions F + CH 3 F and F + CH 2 F 2 has been determined by a competitive method using the F + D 2 reaction as a reference reaction. Ratios of rate constants k F+CH 3 F / k F+D 2 and k F+CH 2
Autor:
Avigdor Persky, Haya Kornweitz
Publikováno v:
Chemical Physics Letters. 331:132-136
Three-center semi-empirical LEPS potential energy surfaces were constructed for the F + HX ( X = OH ) and F+OH reactions. Trajectory calculations on these surfaces reproduced quite well the available experimental results with regard to rate constants
Autor:
Avigdor Persky, Haya Kornweitz
Publikováno v:
Chemical Physics Letters. 307:479-483
The F+H 2 S reaction is modeled by an F+HX three-center LEPS potential energy surface. Trajectory calculations carried out on this surface reproduced quite well the experimental results with regard to rate constants and energy distribution among the
Autor:
Avigdor Persky
Publikováno v:
Chemical Physics Letters. 298:390-394
The rate constants for the reactions F+H2S and F+D2S at 298 K were determined by a competitive method using the reaction F+CH4 as a reference reaction. The ratios of rate constants kF+H2S/kF+CH4 and kF+D2S/kF+CH4 were determined by a discharge-flow-m