Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Austin J. Ryan"'
Publikováno v:
Inorganic Chemistry. 60:15635-15645
The reductive reactivity of a Ln(II) ion with a nontraditional 4fn5d1 electron configuration has been investigated by studying reactions of the {GdII(N(SiMe3)2)3]}- anion with a variety of reagents that survey the many reaction pathways available to
Autor:
Joseph W. Ziller, Cory J. Windorff, Austin J. Ryan, Justin C. Wedal, Daniel N. Huh, William J. Evans
Publikováno v:
Journal of Coordination Chemistry. 74:74-91
Eight cyclopentadienyl U(III) iodide complexes have been synthesized from UI3 and crystallographically characterized to show the variations that can occur with this ligand set and uranium in the +3 oxidation state: (C5Me5)2UI(THF), {[K(OEt2)2][(C5Me5
Publikováno v:
Inorganic chemistry. 60(20)
The reductive reactivity of a Ln(II) ion with a nontraditional 4f
Autor:
Austin J, Ryan, Sree Ganesh, Balasubramani, Joseph W, Ziller, Filipp, Furche, William J, Evans
Publikováno v:
Journal of the American Chemical Society. 142(20)
Lanthanide-based dinitrogen reduction chemistry has been expanded by the discovery of the first end-on Ln
Publikováno v:
Chemical science, vol 11, iss 7
Chemical Science
Chemical Science
The use of 18-crown-6 (18-c-6) in place of 2.2.2-cryptand (crypt) in rare earth amide reduction reactions involving potassium has proven to be crucial in the synthesis of Ln(ii) complexes and isolation of their CO reduction products. The faster speed
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::99e3abbecdafadcc667a3ef356515d16
https://escholarship.org/uc/item/60j0s7mc
https://escholarship.org/uc/item/60j0s7mc
Autor:
Jeffrey R. Long, Joseph W. Ziller, Lucy E. Darago, Guo P. Chen, Filipp Furche, Austin J. Ryan, Sree Ganesh Balasubramani, William J. Evans
Publikováno v:
Chemistry – A European Journal. 24:7702-7709
A new series of Ln2+ complexes has been synthesized that overturns two previous generalizations in rare-earth metal reduction chemistry: that amide ligands do not form isolable complexes of the highly reducing non-traditional Ln2+ ions, and that yttr
Publikováno v:
Chemical Communications. 55:2325-2327
New examples of uranium in the +2 oxidation state have been isolated by reduction of Cptet3U (Cptet = C5Me4H) and U(NR2)3 (R = SiMe3). Results show that more donating ligands as well as lower coordination number complexes are viable for U(ii) and sug
Autor:
Juan S. Lezama Pacheco, Gregory L. Wagner, Enrique R. Batista, David H. Woen, Jing Su, Austin J. Ryan, Maryline G. Ferrier, Stosh A. Kozimor, Samantha K. Cary, Jonathan W. Engle, Tonya Vitova, Benjamin W. Stein, Ping Yang, Angela C. Olson, William J. Evans, Megan E. Fieser
Publikováno v:
Chemical Science. 8:6076-6091
The isolation of [K(2.2.2-cryptand)][Ln(C5H4SiMe3)3], formally containing LnII, for all lanthanides (excluding Pm) was surprising given that +2 oxidation states are typically regarded as inaccessible for most 4f-elements. Herein, X-ray absorption nea
Publikováno v:
Chemical communications (Cambridge, England). 55(16)
New examples of uranium in the formal +2 oxidation state have been isolated by reduction of Cptet3U (Cptet = C5Me4H) and U(NR2)3 (R = SiMe3) in the presence of 2.2.2-cryptand (crypt) to produce [K(crypt)][Cptet3U] and [K(crypt)][U(NR2)3], respectivel
Autor:
William J. Evans, Austin J. Ryan
Publikováno v:
Structure and Bonding ISBN: 9783030400248
This chapter describes a personal journey through the periodic table in which an undergraduate starting research in boron hydride chemistry developed into a professorial researcher in rare earth chemistry. The chapter details how the periodic table b
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c096f1bdc7a5d1c6b881667baddab8e6
https://doi.org/10.1007/430_2019_43
https://doi.org/10.1007/430_2019_43