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Autor:
Austin A Kamin, Marcus A. Juhasz
Publikováno v:
Inorganic Chemistry. 59:189-192
The percyanated dodecaborate anion [B12(CN)12]2- was prepared by reacting [B12I12]2- with CuCN in the presence of a palladium catalyst at elevated pressure and temperature in a microwave reactor. The fully cyanated cluster was isolated as a tetraethy