Zobrazeno 1 - 10
of 214
pro vyhledávání: '"Atrane"'
Publikováno v:
Nano Select, Vol 5, Iss 7-8, Pp n/a-n/a (2024)
Abstract The use of triethanolamine in the preparation of materials has been a fertile area of research during the last decades. It is used in sol‐gel synthesis because of its ability to regulate pH, act as a structure‐directing agent, and form a
Externí odkaz:
https://doaj.org/article/d901adbc38654d4fa2a20af3fa99d5e1
Akademický článek
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Publikováno v:
Chemistry, an Asian journal. 16(20)
The synthesis and isolation of atrane-type molecules 1E+ (E=Si, Ge, or Sn) having a cationic group 14 elemental center are reported. The cations 1E+ act as hard and soft Lewis superacids, which readily interact with various hard and soft Lewis basic
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::33663f96e875cdf821d123137efb4e41
https://pubmed.ncbi.nlm.nih.gov/34487429
https://pubmed.ncbi.nlm.nih.gov/34487429
Publikováno v:
Inorganic Chemistry. 58:4244-4252
The syntheses of the novel stannatranes N(CH2CMe2O)3Sn-(1S)-(−)-OC(O)C(OMe)(CF3)(C6H5), 1(S, Δ), and N(CH2CMe2O)3Sn-(1R)-(+)-OC(O)C(OMe)(CF3)(C6H5), 2(R, Λ), and germatranes N(CH2CMe2O)3Ge-(1S)-(−)-OC(O)C(OMe)(CF3)(C6H5), 3(S, Δ), and N(CH2CMe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8eea664788955a91f85123d77377e281
https://doi.org/10.1021/acs.inorgchem.8b03312
https://doi.org/10.1021/acs.inorgchem.8b03312
RESUMEN En este trabajo se investigó la síntesis de xerogeles de sílice por la vía de los atranos, y se evaluó la influencia de la concentración del agente iniciador (HCl) y la presencia o no del surfactante (CTAB), sobre el tiempo de gelificac
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::feff3d35985d11aa5a47b30f3dea6cf5
Publikováno v:
Inorganic Chemistry. 57:10543-10547
Chemical oxidation of cerium complexes can be unpredictable because of labile metal–ligand bonds leading to ligand redistribution. The use of tripodal frameworks such as silyl-substituted tren ligands (NN′3 = [N(CH2CH2N(SiMe2tBu))3]3–) and a tr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1d18bc507733b4918ac9e7fa3c55e974
https://doi.org/10.1021/acs.inorgchem.8b00712
https://doi.org/10.1021/acs.inorgchem.8b00712
Publikováno v:
Organometallics. 37:1708-1718
Tris(1-isopropylbenzimidazol-2-ylthio)methane ([TitmPriBenz]H) is obtained by treatment of 1-isopropyl-1,3-dihydro-2H-benzimidazole-2-thione with NaH followed by CHI3. The reaction of [TitmPriBenz]H with Me2Zn affords the zinc methyl complex [κ3-Tit
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b34fad417478a750a0a49621a4353fec
https://doi.org/10.1021/acs.organomet.8b00158
https://doi.org/10.1021/acs.organomet.8b00158
Publikováno v:
Inorganica Chimica Acta. 475:150-154
Tripodal, tetradentate tetraphosphine ligand tris(1H-2-diisopropylphosphinoimidazol-1-yl)phosphine (1) was synthesized in three straightforward steps from widely available starting materials. The ligand crystallized in a C3-like conformation suitable
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::757d645843cc58ba8b5160ec081ac383
https://doi.org/10.1016/j.ica.2017.10.017
https://doi.org/10.1016/j.ica.2017.10.017
Publikováno v:
Journal of Organometallic Chemistry. 857:5-9
Oxidation of in situ generated CeIII(atrane) (atrane = [N(CH2C(CH3)2O)3]3–) with iodine or FcBArF afforded the novel cationic tetravalent cerium salts [CeIV(atrane)(thf)3][I3] and [CeIV(atrane)(thf)3][BArF], both of which showed coordination by thr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4cb97c3d2972a282bf0b39e0bd01c15c
https://doi.org/10.1016/j.jorganchem.2017.10.017
https://doi.org/10.1016/j.jorganchem.2017.10.017
Publikováno v:
Materials Letters. 206:105-108
An aqueous, one-pot synthesis of encapsulated palladium (Pd) nanoparticles by cerium dioxide (CeO 2 ) is reported. A metalloorganic compound, cerium (IV) atrane, was prepared and used as water-stable CeO 2 precursor. The CeO 2 shell of the synthesize
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2b3dbfe549c208dd6b2c17353054c85b
https://doi.org/10.1016/j.matlet.2017.06.114
https://doi.org/10.1016/j.matlet.2017.06.114