Zobrazeno 1 - 10
of 68
pro vyhledávání: '"Ashwini K. Phukan"'
Publikováno v:
Inorganic Chemistry Frontiers. 9:5673-5687
DFT calculations reveal the power of ylides in stabilizing neutral singlet cyclic borylenes that are found to be capable of activating a variety of small molecules having enthalpically strong bonds.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8dde097c342c76caff23e2da922cc29b
https://doi.org/10.1039/d2qi01511k
https://doi.org/10.1039/d2qi01511k
Autor:
Benedikt Ritschel, Julian Böhnke, Holger Braunschweig, Marcel Härterich, Ashwini K. Phukan, Merle Arrowsmith, Ivo Krummenacher
Publikováno v:
Journal of the American Chemical Society. 143:18339-18345
The ruthenium-catalyzed cross-metathesis of alkenes and alkynes, which splits the alkene C═C double bond and couples one-half to each carbon of the alkyne C≡C triple bond, is one of the most efficient tools for the synthesis of 1,3-dienes, with w
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fb60e2ea2ca2ba1cd7e50cd2015317ea
https://doi.org/10.1021/jacs.1c10131
https://doi.org/10.1021/jacs.1c10131
Publikováno v:
Inorganic Chemistry. 60:12790-12800
Density functional theory calculations have been performed on metallatranes featuring a group 13 elements at the bridgehead position to understand the factors that influence the nature of the M···Z (M = Fe, Co, Ni; Z = Al, Ga, In) interaction pres
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4a119907ec100d469a0c28da7dd14972
https://doi.org/10.1021/acs.inorgchem.1c00977
https://doi.org/10.1021/acs.inorgchem.1c00977
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 28(21)
Computational investigations were carried out to probe the potential of several dicoordinate, singly base-stabilized borylenes of the form [L→BR] (L=neutral Lewis base) in dinitrogen binding. The calculated reaction free energies and activation bar
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6a31d06fe6ad67f96eabe03ff33b42b8
https://pubmed.ncbi.nlm.nih.gov/35344229
https://pubmed.ncbi.nlm.nih.gov/35344229
Publikováno v:
Chemistry – A European Journal. 28
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6bf96cc648dd618aca6f866410eec9b0
https://doi.org/10.1002/chem.202200832
https://doi.org/10.1002/chem.202200832
Publikováno v:
Chemical Science
Base-stabilised borylenes that mimic the ability of transition metals to bind and activate inert substrates have attracted significant attention in recent years. However, such species are typically highly reactive and fleeting, and often cannot be is
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::aa151a633b4570b266fd238a55a93f8f
http://europepmc.org/articles/PMC8162303
http://europepmc.org/articles/PMC8162303
Publikováno v:
Dalton Transactions. 49:13760-13772
Quantum chemical calculations have been carried out on a series of skeletally modified cyclic alkyl amino silylenes (CAASis) and germylenes (CAAGes) to understand their ligand properties and reactivity towards the activation of a variety of small mol
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f2eea6fd0c07c478d78a1f0b5d69fc19
https://doi.org/10.1039/d0dt03043k
https://doi.org/10.1039/d0dt03043k
Autor:
Bitupon Borthakur, Geetha S. Remya, Ashwini K. Phukan, Shahnaz S. Rohman, Bikash Sarmah, Cherumuttathu H. Suresh
Publikováno v:
Organometallics. 38:2770-2781
In recent years, the isolation of nucleophilic boron bases led to a paradigm shift in boron chemistry which prompted us to perform computational studies on a series of bis(carbene) borylene complexes. The structure and electronic properties of these
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::072fc9154047bcae101e1e2206e1bacd
https://doi.org/10.1021/acs.organomet.9b00317
https://doi.org/10.1021/acs.organomet.9b00317
Autor:
Ashwini K. Phukan, Bijoy Ghosh
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 49(27)
Density functional theory calculations are employed to explore the reactivity of metalla-N-heterocyclic carbenes (MNHCs) towards activation of a variety of small molecules (H2, NH3, PH3, SiH3Ph and CH4). All the MNHCs considered are found to have a s
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d5c16e085d02e59bcd8e6ab3cca1f427
https://pubmed.ncbi.nlm.nih.gov/32608419
https://pubmed.ncbi.nlm.nih.gov/32608419
Autor:
Benson, Joseph, Suman, Gomosta, Rini, Prakash, Thierry, Roisnel, Ashwini K, Phukan, Sundargopal, Ghosh
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 26(70)
Treatment of Li[BH
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::b2657567f301a18c86c4f1bd7a8316ea
https://pubmed.ncbi.nlm.nih.gov/32786013
https://pubmed.ncbi.nlm.nih.gov/32786013