Selective catalytic reduction of N2 to N2H4 by a simple Fe complex

Autor: Hill, PJ, Doyle, LR, Crawford, AD, Myers, William, Ashley, AE

The catalytic fixation of N2 by molecular Fe compounds is a rapidly developing field, yet thus far few complexes can effect this transformation, and none are selective for N2H4 production. Herein we report that the simple Fe(0) complex Fe(Et2PCH2CH2P

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::e9b3273d8e038b1d0c3941e5ea041ce8
https://ora.ox.ac.uk/objects/uuid:a155b5cb-0e5b-44b2-9e59-4515c59257eb

Separating electrophilicity and Lewis acidity: the synthesis, characterization, and electrochemistry of the electron deficient tris(aryl)boranes B(C6F5)(3-n)(C6Cl5)n (n = 1-3)

Autor: Ashley, AE, Herrington, TJ, Wildgoose, GG, Zaher, H, Thompson, AL, Rees, NH, Krämer, T, O'Hare, D

A new family of electron-deficient tris(aryl)boranes, B(C(6)F(5))(3-n)(C(6)Cl(5))(n) (n = 1-3), has been synthesized, permitting an investigation into the steric and electronic effects resulting from the gradual replacement of C(6)F(5) with C(6)Cl(5)

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https://ora.ox.ac.uk/objects/uuid:eb9595a9-aaf9-4fff-9860-ab514aab2a0f

A New Mode of Chemical Reactivity for Metal-Free Hydrogen Activation by Lewis Acidic Boranes.

Autor: Bennett EL; School of Chemistry, University of East Anglia, Norwich Research Park, Norwich, NR4 7TJ, UK., Lawrence EJ; School of Chemistry, University of East Anglia, Norwich Research Park, Norwich, NR4 7TJ, UK., Blagg RJ; School of Chemistry, University of East Anglia, Norwich Research Park, Norwich, NR4 7TJ, UK., Mullen AS; School of Chemistry, University of East Anglia, Norwich Research Park, Norwich, NR4 7TJ, UK., MacMillan F; School of Chemistry, University of East Anglia, Norwich Research Park, Norwich, NR4 7TJ, UK., Ehlers AW; Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, PO Box 94157, 1090 GD, Amsterdam, The Netherlands.; Department of Chemistry, Science Faculty, University of Johannesburg, PO Box 254, Auckland Park, Johannesburg, South Africa., Scott DJ; Molecular Sciences Research Hub, Imperial College White City Campus, 80 Wood Lane, London, W12 0BZ, UK., Sapsford JS; Molecular Sciences Research Hub, Imperial College White City Campus, 80 Wood Lane, London, W12 0BZ, UK., Ashley AE; Molecular Sciences Research Hub, Imperial College White City Campus, 80 Wood Lane, London, W12 0BZ, UK., Wildgoose GG; School of Chemistry, University of East Anglia, Norwich Research Park, Norwich, NR4 7TJ, UK., Slootweg JC; Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, PO Box 94157, 1090 GD, Amsterdam, The Netherlands.

Publikováno v: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2019 Jun 17; Vol. 58 (25), pp. 8362-8366. Date of Electronic Publication: 2019 May 13.

Base-induced reversible H 2 addition to a single Sn(ii) centre.

Autor: Turnell-Ritson RC; Department of Chemistry , Imperial College London , London , SW7 2AZ , UK . Email: a.ashley@imperial.ac.uk., Sapsford JS; Department of Chemistry , Imperial College London , London , SW7 2AZ , UK . Email: a.ashley@imperial.ac.uk., Cooper RT; Department of Chemistry , Imperial College London , London , SW7 2AZ , UK . Email: a.ashley@imperial.ac.uk., Lee SS; Department of Chemistry , Imperial College London , London , SW7 2AZ , UK . Email: a.ashley@imperial.ac.uk., Földes T; Research Center for Natural Sciences , Hungarian Academy of Sciences , Magyar tudósok körútja 2 , H-1117 Budapest , Hungary . Email: papai.imre@ttk.mta.hu., Hunt PA; Department of Chemistry , Imperial College London , London , SW7 2AZ , UK . Email: a.ashley@imperial.ac.uk., Pápai I; Research Center for Natural Sciences , Hungarian Academy of Sciences , Magyar tudósok körútja 2 , H-1117 Budapest , Hungary . Email: papai.imre@ttk.mta.hu., Ashley AE; Department of Chemistry , Imperial College London , London , SW7 2AZ , UK . Email: a.ashley@imperial.ac.uk.

Publikováno v: Chemical science [Chem Sci] 2018 Sep 18; Vol. 9 (46), pp. 8716-8722. Date of Electronic Publication: 2018 Sep 18 (Print Publication: 2018).

Reversible coordination of N 2 and H 2 to a homoleptic S = 1/2 Fe(i) diphosphine complex in solution and the solid state.

Autor: Doyle LR; Department of Chemistry , Imperial College London , London SW7 2AZ , UK . Email: a.ashley@imperial.ac.uk., Scott DJ; Department of Chemistry , Imperial College London , London SW7 2AZ , UK . Email: a.ashley@imperial.ac.uk., Hill PJ; Department of Chemistry , Imperial College London , London SW7 2AZ , UK . Email: a.ashley@imperial.ac.uk., Fraser DAX; Department of Chemistry , Imperial College London , London SW7 2AZ , UK . Email: a.ashley@imperial.ac.uk., Myers WK; Inorganic Chemistry Laboratory , University of Oxford , Oxford OX1 3QR , UK., White AJP; Department of Chemistry , Imperial College London , London SW7 2AZ , UK . Email: a.ashley@imperial.ac.uk., Green JC; Inorganic Chemistry Laboratory , University of Oxford , Oxford OX1 3QR , UK., Ashley AE; Department of Chemistry , Imperial College London , London SW7 2AZ , UK . Email: a.ashley@imperial.ac.uk.

Publikováno v: Chemical science [Chem Sci] 2018 Jul 18; Vol. 9 (37), pp. 7362-7369. Date of Electronic Publication: 2018 Jul 18 (Print Publication: 2018).