Zobrazeno 1 - 10
of 48
pro vyhledávání: '"Arumugam, Jayaraman"'
Publikováno v:
ACS Omega, Vol 2, Iss 11, Pp 7849-7861 (2017)
Externí odkaz:
https://doaj.org/article/337ae9fa84144005a099832aef3f2f53
Autor:
Debabrata Dhara, Arumugam Jayaraman, Marcel Härterich, Merle Arrowsmith, Malte Jürgensen, Maximilian Michel, Holger Braunschweig
Publikováno v:
Chemistry – A European Journal.
Autor:
Alexander Okorn, Arumugam Jayaraman, Lukas Englert, Merle Arrowsmith, Theresa Swoboda, Jeanette Weigelt, Carina Brunecker, Merlin Hess, Anna Lamprecht, Carsten Lenczyk, Maximilian Rang, Holger Braunschweig
Publikováno v:
Chemical Science. 13:7566-7574
In contrast to classical B–B bond-centred diborene hydrogenation, polycyclic aromatic hydrocarbon-substituted diborenes first undergo thermal intramolecular hydroarylation, followed by hydrogenation of the remaining B–B and endocyclic B–C bonds
Autor:
Stephanie Kachel, Arumugam Jayaraman, Alexander Okorn, Ivo Krummenacher, Regina Drescher, Carina Brunecker, Sonja Fuchs, Merlin Heß, Tom E. Stennett, Holger Braunschweig
Publikováno v:
Chemical Communications. 58:2331-2334
Unprecedented direct indole formation from the thermal reaction of an electron-rich alkyne with aryl azides has been discovered, involving triazole-derived imino carbenes.
Autor:
Ramapada Dolai, Rahul Kumar, Benedict J. Elvers, Pradeep Kumar Pal, Benson Joseph, Rina Sikari, Mithilesh Kumar Nayak, Avijit Maiti, Tejender Singh, Nicolas Chrysochos, Arumugam Jayaraman, Ivo Krummenacher, Jagannath Mondal, U. Deva Priyakumar, Holger Braunschweig, Cem B. Yildiz, Carola Schulzke, Anukul Jana
Publikováno v:
Chemistry – A European Journal. 29
Herein, a new type of carbodicarbene (CDC) comprising two different classes of carbenes is reported; NHC and CAAC as donor substituents and compare the molecular structure and coordination to Au(I)Cl to those of NHC-only and CAAC-only analogues. The
Autor:
Alexandra Friedrich, Todd B. Marder, Udo Radius, Florian Kerner, Arumugam Jayaraman, Yudha P. Budiman
Publikováno v:
Journal of the American Chemical Society. 142:6036-6050
C–C reductive elimination from [PdL2(C6F5)2] to form polyfluorinated biaryls has been a challenge for over 50 years. Thus, palladium-catalyzed homocoupling of arylboronates (ArF–Bpin) containing tw...
Autor:
Sonja Fuchs, Arumugam Jayaraman, Ivo Krummenacher, Laura Haley, Marta Baštovanović, Maximilian Fest, Krzysztof Radacki, Holger Helten, Holger Braunschweig
Publikováno v:
Chemical science. 13(10)
We report that the outcome of the tin-boron exchange reaction of a mixed thiophene-benzo-fused stannole with aryldibromoboranes is associated with the steric bulk of the aryl substituent of the borane reagent, leading to either boroles or large dibor
Autor:
Wei Lu, Arumugam Jayaraman, Felipe Fantuzzi, Rian D. Dewhurst, Marcel Härterich, Maximilian Dietz, Stephan Hagspiel, Ivo Krummenacher, Kai Hammond, Jingjing Cui, Holger Braunschweig
Publikováno v:
Angewandte Chemie. 134
Autor:
Stephan Hagspiel, Kai Hammond, Marcel Härterich, Ivo Krummenacher, Wei Lu, Jingjing Cui, Arumugam Jayaraman, Maximilian Dietz, Felipe Fantuzzi, Rian D. Dewhurst, Holger Braunschweig
Publikováno v:
Angewandte Chemie (International ed. in English). 61(3)
A one-pot synthesis of a CAAC-stabilized, unsymmetrical, cyclic diborene was achieved via consecutive two-electron reduction steps from an adduct of CAAC and B\(_2\)Br\(_4\)(SMe\(_2\))\(_2\). Theoretical studies revealed that this diborene has a cons
Publikováno v:
Organometallics. 37:4699-4710
While alkyne insertion into metal–carbon(sp2) bonds is common in transition metal chemistry, direct alkyne insertions into E–C(sp2) bonds are very rare in main group chemistry. Herein, we report a direct alkyne insertion reaction into the P–C(a