Zobrazeno 1 - 10
of 37
pro vyhledávání: '"Arseni Kostenko"'
Publikováno v:
Angewandte Chemie International Edition
Publikováno v:
Journal of the American Chemical Society.
A novel nontransient acyclic iminosilylene (
Publikováno v:
Dalton Transactions. 50:14842-14848
Two new bidentate ferrocene-bridged bis(N-heterocyclic carbene–phospinidenes) (bisNHCPs) were successfully isolated by treating 1,1′-bis-(dichlorophosphine)ferrocene with N-heterocyclic carbenes, followed by dechlorination using sodium naphthalen
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
Chelating phosphines have long been a mainstay as efficient directing ligands in transition‐metal catalysis. Low‐valent derivatives, namely chelating phosphinidenes, are to date unknown, and could lead to chelating complexes containing more than
Publikováno v:
Journal of the American Chemical Society. 142:16935-16941
The first dibenzo[a,e]disilapentalene with two Si═C moieties in the heteropentalene core has been prepared. Its solid-state structure and density functional theory (DFT) calculations revealed that the Si═C bonds are involved in an expanded π-con
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
The versatile cycloaddition chemistry of the Si−Ni multiple bond in the acyclic (amido)(chloro)silylene→Ni0 complex 1, [(TMSL)ClSi→Ni(NHC)2] (TMSL=N(SiMe3)Dipp; Dipp=2,6‐iPr2C6H4; NHC=C[(iPr)NC(Me)]2), toward unsaturated organic substrates is
An easily isolable silacycloheptatriene (silepin) 1 b was synthesized from the reaction of a N-heterocyclic imino (IPrN) substituted tribromosilane IPrNSiBr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::eed5bbe8ce7fe7ab1d806442c4cb6ad7
https://mediatum.ub.tum.de/1707505
https://mediatum.ub.tum.de/1707505
Autor:
Matthias Driess, Luisa Giarrana, Tobias Gensch, Shenglai Yao, Marcel-Philip Luecke, Arseni Kostenko
Publikováno v:
Angewandte Chemie. 134
The reactivity of the 1,4-substituted bis(silylenyl)terphenylene 1 , 1,4-[ ortho -(LSi)C 6 H 4 ] 2 C 6 H 4 , (L = RC(NtBu) 2 , R = Ph, Mes) towards CS 2 is reported. The latter results in a de-aromatization of the phenylene ring, affording the.