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Publikováno v:
Synthesis. 54:965-974
We have developed a regio- and stereoselective thermal [3+2]-cycloaddition protocol involving acetoxy allenoates as 1,2-dipoles under metal-free conditions for the synthesis of 1,4,5-tri/1,5-disubstituted 1,2,3-triazoles. δ-Acetoxy allenoates act as