Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Arno N J, Blok"'
Publikováno v:
Organometallics. 22:2564-2570
A theoretical study of ethene trimerization at a cationic (C6H5CH2C5H4)Ti fragment generally supports the metallacycle mechanism proposed earlier for this reaction. However, the crucial formation of the 1-hexene complex from a titanacycloheptane inte
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f08ed36526fed3b5ee4b4729fb3bdcdd
https://doi.org/10.1021/om030049o
https://doi.org/10.1021/om030049o
Publikováno v:
Organometallics. 21:4939-4949
In this paper we present a systematic comparison of the performance of different computational approaches to study the propagation and termination reactions of olefins with a prototype homogeneous group 4 ansa-metallocene catalyst. Chain propagation,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1d4ee0ea47607d06b0b1cc2d14a18dd2
https://doi.org/10.1021/om020315i
https://doi.org/10.1021/om020315i
Autor:
Bas, de Bruin, Theo P J, Peters, Simone, Thewissen, Arno N J, Blok, Jos B M, Wilting, René, de Gelder, Jan M M, Smits, Anton W, Gal
Publikováno v:
Angewandte Chemie (International ed. in English). 41(12)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::21c18ada06d8d947f6b8ec345068a626
https://pubmed.ncbi.nlm.nih.gov/19746620
https://pubmed.ncbi.nlm.nih.gov/19746620
Autor:
Simone Thewissen, Eduard J. Reijerse, René de Gelder, Jan M. M. Smits, Arno N. J. Blok, Jasper Kaiser, Theo P. J. Peters, Dennis G. H. Hetterscheid, Bas de Bruin
Publikováno v:
Journal of the American Chemical Society, 127, 6, pp. 1895-1905
Journal of the American Chemical Society, 127, 1895-1905
Journal of the American Chemical Society, 127, 1895-1905
One-electron oxidation of [(Me(n)tpa)Ir(I)(ethene)]+ complexes (Me(3)tpa = N,N,N-tri(6-methyl-2-pyridylmethyl)amine; Me(2)tpa = N-(2-pyridylmethyl)-N,N,-di[(6-methyl-2-pyridyl)methyl]-amine) results in relatively stable, five-coordinate Ir(II)-olefin
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dfc0dc1ca1cefadb469b8187ed50ee2d
https://doi.org/10.1021/ja0439470
https://doi.org/10.1021/ja0439470
Autor:
Peter H. M. Budzelaar, Arno N. J. Blok
A DFT study of the oxidation of (tpa)M-I(C2H4)(+) and (dpa-R)M-I(cod)(+) complexes (M = Rh, Ir) by H2O2 indicates that the reaction starts with heterolytic cleavage of the peroxide O-O bond, leading to M-III(olefin)(OH)(2+) species. These can then un
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3acb884bc9d3098c77dfb3c9d157ae95
http://hdl.handle.net/11588/701200
http://hdl.handle.net/11588/701200
Autor:
Peter H. M. Budzelaar, Arno N. J. Blok
Publikováno v:
European Journal of Inorganic Chemistry; Jun2004, Vol. 2004 Issue 11, p2385-2391, 7p