Výsledky vyhledávání - "Arianna Sinibaldi"

Synergistic Strategies in Aminocatalysis

Autor: Antonio Del Vecchio, Arianna Sinibaldi, Valeria Nori, Giuliana Giorgianni, Graziano Di Carmine, Fabio Pesciaioli

Publikováno v: Chemistry (Weinheim an der Bergstrasse, Germany). 28(49)

Synergistic catalysis offers the unique possibility of simultaneous activation of both the nucleophile and the electrophile in a reaction. A requirement for this strategy is the stability of the active species towards the reaction conditions and the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ac692c30ad129e0733be0535350784b8
https://pubmed.ncbi.nlm.nih.gov/35666172

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Impact of Design of Experiments in the optimisation of catalytic reactions in academia

Autor: Armando Carlone, Valeria Nori, Arianna Sinibaldi, Fabio Pesciaioli

Design of Experiments (DoE) is extensively and routinely used in industry; however, in recent decades, it has gained increasing interest from academia in organic synthesis. The use of chemometrics is an attractive strategy to find the real optimum in

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4691d39aefa967ad88b3aea6972afb66
http://hdl.handle.net/11697/175773

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DoE-Driven Development of an Organocatalytic Enantioselective Addition of Acetaldehyde to Nitrostyrenes in Water

Autor: Valeria Nori, Arianna Sinibaldi, Giuliana Giorgianni, Fabio Pesciaioli, Francesca Di Donato, Emanuele Cocco, Alessandra Biancolillo, Aitor Landa, Armando Carlone

Publikováno v: Chemistry (Weinheim an der Bergstrasse, Germany). 28(24)

The development of an enantioselective enamine-catalysed addition of masked acetaldehyde to nitroalkenes via a rational approach helped to move away from the use of chloroform. The presented research allows the use of water as a reaction medium, ther

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bc415e8b926d43cecb8bf684a60e0403
https://pubmed.ncbi.nlm.nih.gov/35230722

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Asymmetric Organocatalysis Accelerated via Self-Assembled Minimal Structures

Autor: Fabio Pesciaioli, Francesco Fini, Francesca Della Penna, Arianna Sinibaldi, Marco Ponzetti, Silvia Marchesan, Armando Carlone, Andrea Baschieri

Self-assembling minimalistic peptides embedded with an organocatalytic moiety were designed. By controlling the formation of fibrils via external intervention, it was shown that the activation is accelerated when the organocatalyst is in its supramol

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::179dea0be3ddeb6ab3677c6ef4f561b7
https://hdl.handle.net/11368/2997541

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Boron-Based Lewis Acid Catalysis: Challenges and Perspectives

Autor: Valeria Nori, Fabio Pesciaioli, Arianna Sinibaldi, Giuliana Giorgianni, Armando Carlone

Publikováno v: Catalysts, Vol 12, Iss 5, p 5 (2022)

In the last two decades, boron-based catalysis has been gaining increasing traction in the field of organic synthesis. The use of halogenated triarylboranes as main group Lewis acid catalysts is an attractive strategy. It has been applied in a growin

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f28b3acda386cf37f6891d3a4bbccf56
https://doi.org/10.3390/catal12010005

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