Zobrazeno 1 - 10
of 193
pro vyhledávání: '"Appel reaction"'
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 19, Iss 1, Pp 91-99 (2023)
Cholesterol reacts under Appel conditions (CBr4/PPh3) to give 3,5-cholestadiene (elimination) and 3β-bromocholest-5-ene (substitution with retention of configuration). Thus, the bromination of cholesterol deviates from the stereochemistry of the sta
Externí odkaz:
https://doaj.org/article/928a1fabf1d64cb48e6a798167d725be
Akademický článek
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Autor:
Yulia V. Khoroshunova, Denis A. Morozov, Andrey I. Taratayko, Sergey A. Dobrynin, Ilia V. Eltsov, Tatyana V. Rybalova, Yulia S. Sotnikova, Dmitriy N. Polovyanenko, Nargiz B. Asanbaeva, Igor A. Kirilyuk
Publikováno v:
Molecules, Vol 26, Iss 19, p 6000 (2021)
Activation of a hydroxyl group towards nucleophilic substitution via reaction with methanesulfonyl chloride or PPh3-CBr4 system is a commonly used pathway to various functional derivatives. The reactions of (5R(S),6R(S))-1-X-6-(hydroxymethyl)-2,2-dim
Externí odkaz:
https://doaj.org/article/16e2e03af9cc40ca86af1d100a8219e9
Autor:
Jamnik, Lana
V diplomski nalogi sem opisala eno od možnih sinteznih poti do (R)-2-(2-bromoetil)-1,1-dimetil-5-metilenciklopentana iz komercialno lahko dostopne kafre. Opisala sem vse sintezne korake s poudarkom na Appelovi reakciji. Večji del te sinteze sem izv
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=od______3505::3bd0a5154dd53a2100690c364d515296
https://repozitorij.uni-lj.si/IzpisGradiva.php?id=147072
https://repozitorij.uni-lj.si/IzpisGradiva.php?id=147072
Autor:
Schumacher, Christian, Ward, Jas S, Rissanen, Kari, Bolm, Carsten, Ramadan El Sayed Aly, Mohamed
Cholesterol reacts under Appel conditions (CBr4/PPh3) to give 3,5-cholestadiene (elimination) and 3β-bromocholest-5-ene (substitution with retention of configuration). Thus, the bromination of cholesterol deviates from the stereochemistry of the sta
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=od______1222::8d8b6dc4bde4e8a2419a28da8e599be3
http://urn.fi/URN:NBN:fi:jyu-202302061643
http://urn.fi/URN:NBN:fi:jyu-202302061643
Publikováno v:
Synthetic Communications. 51:2975-2983
An efficient and facile method has been developed for the synthesis of chiral β-amino bromides from their corresponding alcohols under Appel reaction conditions. This approach allows for the deoxyb...
Autor:
Xuanshu Xia, Patrick H. Toy
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 10, Iss 1, Pp 1397-1405 (2014)
Heterogeneous polymer-supported triphenylphosphine oxides based on the rasta resin architecture have been synthesized, and applied as reagent precursors in a wide range of halogenation reactions. The rasta resin–triphenylphosphine oxides were react
Externí odkaz:
https://doaj.org/article/6ddd2ed20d8a4bbd9d05d4ba5141ccfa
Publikováno v:
Molecules, Vol 19, Iss 2, Pp 2434-2444 (2014)
Synthetic routes to 5'-azidoribonucleosides are reported for adenosine, cytidine, guanosine, and uridine, resulting in a widely applicable one-pot methodology for the synthesis of these and related compounds. The target compounds are appropriate as p
Externí odkaz:
https://doaj.org/article/9888bcd8b7ef41bd9f50f9f00d743903
Publikováno v:
Inorganic Chemistry. 60:5014-5020
Novel trispirocyclotriphosphazenes with oxaphosphorine rings (DOP-PZs) were successfully synthesized by an Appel reaction with phosphoramide, which was prepared from ammonia and 10-chloro-9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide derived fro
Autor:
Sergey A. Dobrynin, Igor A. Kirilyuk, Denis A. Morozov, Andrey I. Taratayko, Dmitriy N. Polovyanenko, Yulia S. Sotnikova, Tatyana V. Rybalova, Yulia V. Khoroshunova, Nargiz B. Asanbaeva, Ilia V. Eltsov
Publikováno v:
Molecules, Vol 26, Iss 6000, p 6000 (2021)
Molecules
Volume 26
Issue 19
Molecules
Volume 26
Issue 19
Activation of a hydroxyl group towards nucleophilic substitution via reaction with methanesulfonyl chloride or PPh3-CBr4 system is a commonly used pathway to various functional derivatives. The reactions of (5R(S),6R(S))-1-X-6-(hydroxymethyl)-2,2-dim