Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Anwar Abo-Amer"'
Publikováno v:
Inorganics, Vol 12, Iss 1, p 32 (2024)
The organoplatinum chemistry of the ligands 2-C5H4N-CH2-NH-C6H3-2-OH-5-X (L1, X = H; L3, X = NO2) and 2-C5H4N-CH=N-C6H3-2-OH-5-X (L2, X = H; L4, X = NO2), which contain an appended phenol substituent, is described. Comparisons are made between the li
Externí odkaz:
https://doaj.org/article/ea33d4141efc4ca0a226565a0ede0988
Publikováno v:
Acta Crystallographica Section E, Vol 70, Iss 7, Pp o770-o770 (2014)
The title compound, C17H26BrNO, exhibits a small twist between the amide residue and the benzene ring [C—N—C—C torsion angle = 29.4 (5)°]. In the crystal, the amido NH group is involved in N—H...O hydrogen bonding, which connects molecules i
Externí odkaz:
https://doaj.org/article/d654cf6d4762425bbfc578db1e8fe7f6
Autor:
Anwar Abo-Amer
Publikováno v:
Acta Crystallographica Section E, Vol 66, Iss 2, Pp m172-m172 (2010)
In the title compound, [Pt(CH3)2(C18H15As)2], the PtII atom adopts a distorted cis-PtAs2C2 square-planar coordination geometry. In the crystal, molecules interact via aromatic π–π stacking interactions [centroid–centroid separation = 3.6741 (18
Externí odkaz:
https://doaj.org/article/7dd6bff702ff488fb709725c91232667
Publikováno v:
Polyhedron. 217:115722
Publikováno v:
Inorganica Chimica Acta. 473:51-59
The ligands RN(CH2-2-C5H4N)2, L1, R = CH2C6H4-2-OH; L2, R = CH2C6H3-4-Me-2-OH; L3, R = CH2C6H3-5-Cl-2-OH; L4, R = CH2C6H3-5-NO2-2-OH; give dimethylplatinum(II) complexes that activate dioxygen in the absence of a protic solvent. The initial reaction
Publikováno v:
Inorganica Chimica Acta. 522:120387
Notable differences are observed in reactions of platinum(II) precursor complexes with pyridine-imine ligands of formula 2-C5H4NCH = NCH2-C6H4OR with R = Me or H. The ligand 2-C5H4NCH = N-2-C6H4OMe, L1, gave simple complexes [PtXY(L1)], XY = Me,Me; M
Publikováno v:
Inorganica Chimica Acta. 507:119580
A rare example of the oxidation of a monomethylplatinum(II) complex with dioxygen is reported, aided by an appended phenol group. The ligands X-2-HO-C6H3CH2N(CH2-2-C5H4N)2 (L1, X = H; L2, X = 5-Cl; L3, X = 5-NO2; L4, X = 4-Me) react with [PtClMe(SMe2
Publikováno v:
Inorganic Chemistry Communications. 61:193-196
The oxidation of [PtMe2(bu2bipy)] with XeF2 in dichloromethane or acetonitrile solution has given crystals of trans-[PtFClMe2(bu2bipy)] or trans-[PtF{NHC( O)Me}ClMe2(bu2bipy)] respectively, but none of the expected product [PtF2Me2(bu2bipy)]. It is s
Publikováno v:
Journal of Organometallic Chemistry. 770:79-84
The oxidative addition of alkyl bromides, RBr, to the dimethylplatinum(II) complex [PtMe 2 (bpox)], 1,bpox ¼ 2,5-bis(2-pyridyl)-1,3,4-oxadiazole gave the corresponding organoplatinum(IV) complexes[PtBrMe 2 (R)(bpox)], R ¼ CH 2 e4-C 6 H 4 C(]O)NHCH
Autor:
Richard J. Puddephatt, Anwar Abo-Amer
Publikováno v:
Journal of Inorganic and Organometallic Polymers and Materials. 24:114-120
The oxidative addition of compounds RBr to [PtMe2(bpox)], 1, bpox = 2,5-bis(2-pyridyl)-1,3,4-oxadiazole gave the corresponding organoplatinum(IV) complexes [PtBrMe2(R)(bpox)], 2, R = CH2CO2H; 3, R = CH2-4-C6H4CO2H; 4, R = CH2-4-C6H4CH2CO2H, whereas t