Zobrazeno 1 - 10
of 163
pro vyhledávání: '"Antonius P.G. Kieboom"'
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 108:57-60
The structural changes of coordination compounds of polyhydroxy carboxylic acids as a function of the pH are discussed. A general coordination-ionization scheme, based on literature data and covering some forty cations, is provided. The following tre
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 93:186-189
The hydrogenolysis of trans-1,2-dimethyl-1,2-diphenylcyclopropane has been studied using palladium, platinum, rhodium and Raney-nickel as the catalysts. The latter three metals show a rather low stereospecificity, i.e. 40% suprafacial versus 60% anta
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 109:518-522
The oxidation of sucrose with periodate was studied at different pH and temperature. Open-chain di- and tetraaldehydes thus obtained were analyzed using HPLC. The ratio of singly oxidized glucose rings to doubly oxidized glucose rings proved to be de
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 88:52-61
The hydrogenation of some forty aromatic ketones to the corresponding alcohols has been studied in ethanol using carbon-supported palladium as the catalyst. Zero order kinetics with respect to ketone is observed. For acetophenones electronic substitu
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 110:271-274
The decomposition of D-ribo-3-hexosulose in water, studied by HPLC, gave D-ribulose (60-65%) and D-erythronic acid (20%), both isolated by column chromatography. D-Ribulose was characterized using LC-MS and NMR. From the latter technique, the ratio o
Autor:
H. van Bekkum, Antonius P.G. Kieboom
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 103:1-12
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 101:339-342
Cis- and trans-2,5-diallyloxy-2,5-dihydrofuran have been prepared by acid catalyzed transacetalization of 2,5-dimethoxy-2,5-dihydrofuran with allyl alcohol. As a by-product, 1,1,3-triallyloxypropane was formed from 2-allyloxy-2,5-dihydrofuran interme
Autor:
Antonius P.G. Kieboom, H. van Bekkum
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 88:1424-1436
The dehydration of a series of 2-aryl-3-methyl-2-butanols and the subsequent isomerization of the 2-aryl-3-methyl-l-butenes primarily formed to the corresponding 2-butenes have been studied in sulfuric acid-acetic acid and in dimethyl sulfoxide. The
Autor:
W.M.M.J. Bovée, J. A. Peters, H. Vroon, C. A. M. Vijverberg, Antonius P.G. Kieboom, H. van Bekkum
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 102:255-263
The complexation of trisodium (carboxymethoxy)succinate (Na3CMOS) with calcium(II) and with lanthanide(III) cations has been studied using NMR spectroscopy. Structural information has been obtained from lanthanide-induced shifts (LIS), T1 relaxation
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 106:35-43
A new kinetic model for the alkaline isomerization and degradation of monosaccharides is presented which includes the interconversion of D-glucose, D-fructose, D-mannose and D-psicose. Computer simulations using this model fit the experimental data a