Zobrazeno 1 - 9 of 9 pro vyhledávání: '"Antonio Cusanelli"'
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Akademický článek
Ligand Effects on the Rate and Mechanism of Solvent Exchange at Rhodium(III) and Iridium(III)
Autor: Antonio Cusanelli, Lynda Nicula-Dadci, Urban Frey, André E. Merbach
Publikováno v: CHIMIA, Vol 50, Iss 12 (1996)
The rate constants and activation parameters for solvent exchange for a series of RhIII and IrIII complexes of the form [M(H2O)6]3+ (M = Rh or Ir) and [Cp*M(S)3]2+ (M = Rh or Ir, and S = H2O, MeCN, or Me2SO) have been determined by NMR spectroscopy
Externí odkaz: https://doaj.org/article/267a0e4acfab46ad90f3087c17e32a0b
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2
Rhodium(III) and Iridium(III) Solvates of the Form [(η5-C5Me5)M(S)3]2+ as Models for the Reactivity of Half-Sandwich Compounds1
Autor: Antonio Cusanelli, Lynda Nicula-Dadci, Urban Frey, Andre E. Merbach
Publikováno v: Inorganic Chemistry. 36:2211-2217
Solvent exchange on the half-sandwich organic solvates [(eta(5)-C(5)Me(5))M(S)(3)](2+) (M = Rh, S = MeCN (1) or Me(2)SO (3); and M = Ir, S = MeCN (2) or Me(2)SO (4)) has been investigated as a function of temperature, pressure, and concentration of f
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e1e3fd0d35126c30634c6cdf97a7aa58
https://doi.org/10.1021/ic961380l
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3
Cis and Trans Rhenium Hydrido Dinitrogen Complexes from Protonation Reactions of Cp*Re(PMe3)2(N2)
Autor: Antonio Cusanelli, Derek Sutton
Publikováno v: Organometallics. 15:3717-3722
The dinitrogen complex Cp*Re(PMe3)2(N2) (1) undergoes protonation at rhenium but not at the rhenium-bound dinitrogen ligand under conditions described here. Protonation by using CF3CO2H, HBF4·OEt2, or CF3SO3H at 213 K afforded the respective rhenium
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::58c72bebcccfa2577732ed63938a2190
https://doi.org/10.1021/om960185b
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4
The Slowest Water Exchange at a Homoleptic Mononuclear Metal Center: Variable-Temperature and Variable-Pressure 17O NMR Study on [Ir(H2O)6]3+
Autor: Andre E. Merbach, David T. Richens, Urban Frey, Antonio Cusanelli
Publikováno v: Journal of the American Chemical Society. 118:5265-5271
The rate constants and activation parameters for water exchange on hexaaqua and monohydroxy pentaaqua iridium(III) have been determined by 17O NMR spectroscopy as a function of temperature (358−406 K) and pressure (0.1−210 MPa) at several aciditi
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7862534652d6f2281e33c09e721c0bd5
https://doi.org/10.1021/ja954071n
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5
End-to-End Rotation of Rhenium-Bound Dinitrogen
Autor: Derek Sutton, Antonio Cusanelli
Publikováno v: Organometallics. 15:1457-1464
The singly 15N-labeled dinitrogen complexes Cp‘Re(CO)(L)(15N14N) (Cp‘ = η5-C5H5, L = CO (1-15Nα) and Cp‘ = η5-C5Me5, L = CO (2-15Nα), PMe3 (3-15Nα), or P(OMe)3 (4-15Nα)) were synthesized from the corresponding aryldiazenido complex [Cp‘
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b862112e2bf741c1cdf434a2ba595539
https://doi.org/10.1021/om950792j
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9
Unprecedented dimethyl sulfoxide conformational equilibria and kinetics on [Ir(Me2SO)3(η-C5Me5)][PF 6]2
Autor: Urban Frey, Antonio Cusanelli, Andre E. Merbach
Publikováno v: Chemical Communications. :379-380
Intermolecular dimethyl sulfoxide exchange on [Ir(Me 2 - SO) 3 (η-C 5 Me 5 ][PF 6 ] 2 1 proceeds via a dissociative mechanism, exclusively from a conformational isomer of 1 (1c) which is itself in equilibrium with a second more compact conformer (1a
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0384ffeec2be82aefddd7d1437a9c8b0
https://doi.org/10.1039/a606982g
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