Zobrazeno 1 - 10
of 55
pro vyhledávání: '"Anton W, Gal"'
Publikováno v:
Angewandte Chemie. 116:4236-4251
Die Oxygenierung der C-H- und CC-Bindungen von Kohlenwasserstoffen, meist mit H2O2 und O2, ist ein wichtiger industrieller Prozess zur Uberfuhrung von Mineralol in hochwertige Chemikalien. Trotz ihrer enormen wirtschaftlichen Bedeutung (und einer ent
Autor:
Dennis G. H. Hetterscheid, Erik Schwartz, Peter H. M. Budzelaar, Anton W. Gal, Quinten Knijnenburg, T. Martijn Kooistra
Publikováno v:
Inorganica Chimica Acta, 357, 2945-2952
Inorganica Chimica Acta, 357, 10, pp. 2945-2952
Inorganica Chimica Acta, 357, 10, pp. 2945-2952
Item does not contain fulltext The formation and reactivity of pyridine diimine rhodium(l) alkyl complexes without beta-hydrogens (Me, Bz, CH2SiMe3) is described. In contrast to the corresponding cobalt complexes, the rhodium complexes could not be a
Autor:
Peter H. M. Budzelaar, C.J. Elsevier, J.M. Ernsting, E.J. Zijp, Kees Vrieze, B. de Pater, Hans-Werner Frühauf, Anton W. Gal
Publikováno v:
Organometallics, 23(2), 269-279. American Chemical Society
Oxidative addition reactions with the highly nucleophilic complex [RhI(Cl)(4‘-(4-tert-butylphenyl)-2,2‘:6‘,2‘ ‘-terpyridine)] (1) and alkyl halides containing chlorine and bromine atoms gave mixtures of uncharacterized products. In contrast
Publikováno v:
Organometallics. 22:2564-2570
A theoretical study of ethene trimerization at a cationic (C6H5CH2C5H4)Ti fragment generally supports the metallacycle mechanism proposed earlier for this reaction. However, the crucial formation of the 1-hexene complex from a titanacycloheptane inte
Autor:
Johan Hoogboom, Jan M. M. Smits, P. P. J. Schlebos, Sandra I. ter Beek, Timo J. J. Sciarone, René de Gelder, Monique Krom, Ruud G. E. Coumans, Theo P. J. Peters, Anton W. Gal
Publikováno v:
European Journal of Inorganic Chemistry. 2003:1072-1087
The ethene complexes [MI(CH2CH2)]+ (M = Ir, Rh) can be oxygenated by molecular oxygen or air in the solid state, to form isolable unsubstituted 3-metalla-1,2-dioxolanes [MIII(CH2CH2OO-κ2C1,O2)]+. Such selectivity could not be achieved in solution. T
Autor:
Jan M. M. Smits, Koen F. W. Hekking, Bas de Bruin, Peter H. M. Budzelaar, T. Martijn Kooistra, René de Gelder, Quinten Knijnenburg, Anton W. Gal
Publikováno v:
European Journal of Inorganic Chemistry. 2003:648-655
A number of cobalt(II) chloride complexes of pyridine/amine N3 and N4 donors have been prepared and structurally characterised. Even though they are paramagnetic, assignment of the 1H NMR signals was possible in several cases. With the exception of t
Autor:
Jan M. M. Smits, Anton W. Gal, Peter H. M. Budzelaar, P.R. Hageman, Yuankui Zhang, René de Gelder
Publikováno v:
European Journal of Inorganic Chemistry. 2003:656-665
The reactions of Me3Al and Me3Ga with cis-2,3-dimethylaziridine (1-H), 3-pyrroline (2-H) and pyrrolidine (3-H) have been investigated. At room temperature, monomeric adducts [Me3M·LH] are obtained (M = Al, Ga; L = 1−3). [Me3Al·1-H] is the first e
Autor:
Simone Thewissen, Anton W. Gal, Theo P. J. Peters, Bas de Bruin, Jos B. M. Wilting, Jan M. M. Smits
Publikováno v:
European Journal of Inorganic Chemistry. 2002:2671-2680
New cationic, five-coordinate bis(ethene)iridium(I) complexes [(κ3-Me3-tpa)IrI(ethene)2]+ (12+) and [(κ3-Me2-dpa-Me)IrI(ethene)2]+ (13+) have been prepared {Me3-tpa = N,N,N-tris[(6-methyl-2-pyridyl)methyl]amine, Me2-dpa-Me = N-methyl-N,N-bis[(6-met
Autor:
René de Gelder, Nicolaas N.F.A. Suos, Anton W. Gal, Bas de Bruin, Jan M. M. Smits, Theo P. J. Peters
Publikováno v:
Inorganica Chimica Acta. 337:154-162
The preparation of a series of new amido bridged binuclear complexes [(NNN)RhI 2(cod)2] (cod=Z,Z-1,5-cyclooctadiene), [(NNN)RhI 2(hed)2] (hed=1,5-hexadiene) and [(NNN)RhI 2(CO)4] is reported. These complexes contain chelating imidaz
Autor:
Sander T. H. Willems, Anton W. Gal, René de Gelder, Peter H. M. Budzelaar, Nicolle N. P. Moonen, Jan M. M. Smits
Publikováno v:
Chemistry - A European Journal. 8:1310-1320
The reaction of 14e [L(Me)Rh(coe)] (1; L(Me)[double bond]ArNC(Me)CHC(Me)NAr, Ar[double bond]2,6-Me(2)C(6)H(3); coe[double bond]cis-cyclooctene) with phenyl halides and thiophenes was studied to assess the competition between sigma coordination, arene