Zobrazeno 1 - 10
of 33
pro vyhledávání: '"Anton Lishchynskyi"'
Publikováno v:
The Journal of Organic Chemistry. 83:8150-8160
We herein present a flexible approach for the incorporation of CF3 units into a predefined site of electron-rich alkenes that exploits the regiocontrolled introduction of an iodine handle and subsequent trifluoromethylation of the C(sp2)–I bond usi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3ceaa4d21d506ff4b3a95bba30aeb1e7
https://doi.org/10.1021/acs.joc.8b00927
https://doi.org/10.1021/acs.joc.8b00927
Publikováno v:
The Journal of organic chemistry. 83(15)
We herein present a flexible approach for the incorporation of CF
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::d5a134ea56622f9dd413d7fd01fabc5a
https://pubmed.ncbi.nlm.nih.gov/29916255
https://pubmed.ncbi.nlm.nih.gov/29916255
Autor:
Vladimir V. Grushin, Eduardo C. Escudero-Adán, R. L. Harlow, Eddy Martin, William J. Marshall, Andrey I. Konovalov, Fedor M. Miloserdov, Anton Lishchynskyi, Jordi Benet-Buchholz
Publikováno v:
Helvetica chimica acta, 101(4)
Helvetica chimica acta 101 (2018) 4
Helvetica chimica acta 101 (2018) 4
Due to disorder, [K(crypt-222)]+ CF-3 (1) is crystallographically indistinguishable from its isomer, a 1:1 fluoroform clathrate of deprotonated [K(crypt-222)]+, [K(crypt-222{-H+})]·CHF3 (2). In our preceding publications, 1 was characterized on the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::226a5cf99d2afe349daae2a00b29b6ef
https://research.wur.nl/en/publications/on-the-structure-of-kcrypt-222supsup-cf3
https://research.wur.nl/en/publications/on-the-structure-of-kcrypt-222supsup-cf3
Publikováno v:
Recercat. Dipósit de la Recerca de Catalunya
instname
instname
Acceptor-substituted N–H groups as found in carbamides and sulfonamides are readily activated through suitable unsaturated metal complexes applying the concept of metal–ligand bifunctionality. This process constitutes the basis for an enantiosele
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f981bb3cc01910b936e902e94768852f
https://doi.org/10.1016/j.tet.2015.03.028
https://doi.org/10.1016/j.tet.2015.03.028
Autor:
Anton Lishchynskyi, Vladimir V. Grushin, Marta Martínez Belmonte, Liubov I. Panferova, Fedor M. Miloserdov, Jordi Benet-Buchholz
Publikováno v:
Angewandte Chemie-International Edition 54 (2015) 17
Angewandte Chemie-International Edition, 54(17), 5218-5222
Angewandte Chemie-International Edition, 54(17), 5218-5222
Four new well-defined CuI complexes bearing a C2F5 ligand have been prepared and fully characterized: [(Ph3P)2CuC2F5] (2), [(bpy)CuC2F5] (3), [(Ph3P)Cu(phen)C2F5] (4), and [(IPr)CuC2F5] (5). X-ray structures of all four have been determined, showing
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a347e947ae232885cd2606fa724785a4
https://doi.org/10.1002/ange.201500341
https://doi.org/10.1002/ange.201500341
Autor:
Eddy Martin, Jordi Benet-Buchholz, Eduardo C. Escudero-Adán, Anton Lishchynskyi, Andrey I. Konovalov, Vladimir V. Grushin, Fedor M. Miloserdov
Publikováno v:
Helvetica chimica acta, 100(4)
Helvetica chimica acta 100 (2017) 4
Helvetica chimica acta 100 (2017) 4
[K(crypt-222)]+ CF3- (1) and [K(crypt-222)]+ BF4- (3) are isostructural, displaying nearly identical unit cell parameters. The two structures are similar to the extent that the previously reported [K(crypt-222)]+ CF3- model can be refined against the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d7f9014e065852d43da20701ed47e8f1
https://doi.org/10.1002/hlca.201700032
https://doi.org/10.1002/hlca.201700032
Publikováno v:
Synlett. 26:45-50
A variety of vinylic bromides and iodides undergo smooth trifluoromethylation and pentafluoroethylation with RfH-derived CuRf (Rf = CF3, C2F5) to give the corresponding fluoroalkylated olefins. These reactions employing the low-cost CuRf reagents occ
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::155df5abd674756a17f0fdfa13ef75a4
https://doi.org/10.1055/s-0034-1379497
https://doi.org/10.1055/s-0034-1379497
Autor:
Zahra Mazloomi, Atsushi Urakawa, Vladimir V. Grushin, Pedro Benavente, Atul Bansode, Anton Lishchynskyi
Publikováno v:
Organic Process Research & Development. 18:1020-1026
The first continuous flow process has been developed for the synthesis of a superior trifluoromethylating reagent, “ligandless” CuCF3, from fluoroform, by far the best CF3 source in terms of availa...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ed9bbf68380ed2cb63762f70b537b4b5
https://doi.org/10.1021/op500109v
https://doi.org/10.1021/op500109v
Publikováno v:
Journal of the American Chemical Society. 135:12584-12587
Pentafluoroethane, C2F5H (HFC-125), is smoothly cuprated with preisolated or in situ-generated [K(DMF)][(t-BuO)2Cu] to give [K(DMF)2][(t-BuO)Cu(C2F5)] (1) in nearly quantitative yield. Complex 1 has been isolated, structurally characterized, and demo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e07e3ee787ee8e621d1ad0e5e50f6656
https://doi.org/10.1021/ja407017j
https://doi.org/10.1021/ja407017j
Publikováno v:
Journal of the American Chemical Society. 134:16167-16170
The C-X bond (X = Br, Cl) of α-haloketones is smoothly trifluoromethylated with the fluoroform-derived CuCF(3) reagent recently developed in our laboratories. This is the first nucleophilic α-trifluoromethylation reaction of carbonyl compounds and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c9cbb972cbbae97043639bf8db86f66a
https://doi.org/10.1021/ja307783w
https://doi.org/10.1021/ja307783w