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Reactions of the hydroxide ion OH–(H2O)0,1,2,3, solvated with 0–3 water molecules, have been studied in the gas phase using flow-tube and ion-beam techniques. The reactions studied included proton transfer, nucleophilic displacement and isotope e
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f2177eb54e6a44527e1a96f74294c483
https://doi.org/10.1039/dc9888500037
https://doi.org/10.1039/dc9888500037
Publikováno v:
International Journal of Mass Spectrometry and Ion Processes. 81:101-122
A selected ion flow tube was used to measure the rate constants and product distributions for the reactions of OH− (H2O)n with CH3CN over the temperature range 240–363 K for the case n = 1 and at 298 K for n = 0 and 2. Proton transfer was the onl
Autor:
Albert A. Viggiano, John F. Paulson, Michael. Henchman, Peter M. Hierl, Anton F. Ahrens, D. C. Clary
Publikováno v:
Journal of the American Chemical Society. 108:3140-3142
Proton-transfer reactions which are exothermic in the gas phase are exceedingly efficient - most reacting at essentially every collision. Several studies have shown how this extreme reactivity is influenced by solvation in the gas phase at 300 K. Her
Autor:
Albert A. Viggiano, Peter M. Hierl, John F. Paulson, Michael. Henchman, Anton F. Ahrens, D. C. Clary
Publikováno v:
Chemischer Informationsdienst. 17
Proton-transfer reactions which are exothermic in the gas phase are exceedingly efficient - most reacting at essentially every collision. Several studies have shown how this extreme reactivity is influenced by solvation in the gas phase at 300 K. Her
Autor:
John F. Paulson, Anton F. Ahrens, Peter M. Hierl, D. C. Clary, A. A. Viggiano, Michael Henchman
Publikováno v:
Journal of the American Chemical Society. 108:3142-3143