Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Anthony J. Paine"'
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 34:3061-3069
The basic features of a three-step experimental process to produce supermicron polymer particles are described. First, a submicron emulsifier-free latex is prepared by a well-known technique. Second, the latex is aggregated by destabilizing with cety
Publikováno v:
Journal of Colloid and Interface Science. 177:602-612
In emulsion polymerization processes it is important to control the surfactant level to avoid secondary nucleation (too much surfactant) and coagulation (too little). Persulfate initiators generate two types of surface active sulfate-containing speci
Publikováno v:
Journal of Applied Polymer Science. 58:2047-2055
The emulsion polymerization of large monodisperse MMA/BA copolymer particles by surfactant-free means at high solids content is described. A series of sequential seeded growth reactions were used to obtain monodisperse particles with diameters of at
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 33:2297-2304
A “surfactant-free” emulsion polymerization of methyl methacrylate was conducted at 80°C with ammonium persulfate initiator. The water-soluble MMA-based oligomers re-maining were isolated and analyzed both as-produced and after hydrolysis. NMR a
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 33:1849-1857
The emulsion polymerization of large MMA/BA copolymer particles with narrow particle size distributions and core-shell structure is described. A series of sequential seeded growth emulsion polymerizations were used to obtain monodisperse particles wi
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 33:1597-1606
It is well known that the amount of surfactant must be carefully controlled during starve-fed emulsion polymerization processes. Too little surfactant leads to emulsion instability and coagulation, while too much surfactant leads to secondary particl
Publikováno v:
Journal of the American Oil Chemists’ Society. 72:11-15
Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry was used to characterize nonionic, anionic and cationic surfactants. Rapid mass analyses can be achieved with proper choice of matrix material. The technique is suitable for
Publikováno v:
Langmuir. 9:1468-1472
Autor:
Anthony J. Paine
Publikováno v:
Particle & Particle Systems Characterization. 10:26-32
It is often necessary to estimate the properties of particle size distributions from limited samples taken from large populations. When the distributions are broad, and higher order moments required, as in the case of volume based particle size distr
Publikováno v:
The Canadian Journal of Chemical Engineering. 69:639-647
A non-Newtonian mixture of monomers, their copolymer and pigment was dispersed into water with emulsifier by a rotor-stator homogenizer (Brinkmann Polytron). Volume median diameters d50 of the droplets, measured by Coulter Counter or optical microsco