Výsledky vyhledávání - "Anthony G. Mackie"

The reaction of cobalt powder with tetraiodo {1,2-bis(dibenzylphosphino)ethane} to form 1,2-bis (dibenzylphosphino)ethane cobalt diiodide, Co(dBzP2)I2; and the X-ray crystal structure of the diphosphinodioxide complex, Co{dBzP2(O)2}I2

Autor: Charles A. McAuliffe, Peter T. Ndifon, Robin G. Pritchard, Anthony G. Mackie

Publikováno v: Inorganica Chimica Acta. 282:25-29

The interaction of 1,2-bis(dibenzylphosphino)ethane, (dBzP 2 ) with diiodine in a 1:2 molar ratio leads to the isolation of tetraido {1,2-bis(dibenzylphosphino)ethane}, (dBzP 2 I 4 ) which readily reacts with coarse-grain cobalt powder to yield sky b

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::29677f7b537e0aacfd7491dc872e5ad8
https://doi.org/10.1016/s0020-1693(98)00191-1

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ChemInform Abstract: Diiodophosphoranes. Synthesis and Structure in the Solid State and in Solution

Autor: Stephen M. Godfrey, Robin G. Pritchard, Charles A. McAuliffe, Anthony G. Mackie, Neil Bricklebank, Peter J. Kobryn

Publikováno v: ChemInform. 24

Nineteen diiodophosphoranes, R3PI2(R3= Ph3, substituted triaryl, mixed arylalkyl, or trialkyl), the vast majority of which have previously not been reported, are described. Their 31P{H} NMR data indicate an ionic [R3PI]I structure in CDCl3 solution,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1dca46d9d6216a9efc5a9623ac6b76d7
https://doi.org/10.1002/chin.199315218

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Crystal structures of trinuclear [{MnI2(PPhMe2)1.33}3] and tetranuclear [Mn4(µ4-O)I6(PPhMe2)4] formed by OO bond cleavage by the former

Autor: Anthony G. Mackie, Robin G. Pritchard, Charles A. McAuliffe, Peter T. Ndifon, Philomena P. Matear, Brian Beagley

Publikováno v: J. Chem. Soc., Dalton Trans.. :1301-1304

The unique trinuclear complex [{MnI2(PPhMe2)1.33}3] has been prepared and its crystal structure determined. It consists of a pseudo-octahedral MnI4P2 unit sandwiched by two pseudo-tetrahedral MnI3P units held together by bridging iodines. Under contr

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7267b8fa66e880a8ed7865687582e176
https://doi.org/10.1039/dt9920001301

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The reaction of coarse-grain metal powders with phosphoranes: a facile activation of metallic reagents and a novel route to metal–phosphine complexes. The X-ray crystal structures of Mnl2(PPhMe2) and FeBr3(PPhMe2)2

Autor: Stephen M. Godfrey, Susan M. Watson, David G. Kelly, Robin G. Pritchard, Philomena P. Mac Rory, Charles A. McAuliffe, Anthony G. Mackie

Publikováno v: J. Chem. Soc., Chem. Commun.. :1447-1449

A route to new and existing transition metal phosphine complexes is provided by the reaction of coarse-grain metal powders and phosphoranes in diethyl ether, as exemplified here by Nil3(PMe3)2, FeBr3(PPhMe2)2 and Mnl2(PPhMe2).

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d1a19acc43c37da51bbcf99bf52ef00d
https://doi.org/10.1039/c39910001447

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The structure of triphenylphosphorus–dibromine, the first crystallographically characterised bromophosphorane, a compound which has the novel four-coordinate molecular Ph3P–Br–Br geometry

Autor: Neil Bricklebank, Robin G. Pritchard, Stephen M. Godfrey, Charles A. McAuliffe, Anthony G. Mackie

Publikováno v: J. Chem. Soc., Chem. Commun.. :355-356

Triphenylphosphorus–dibromine is shown by X-ray crystallography to have a four-coordinate Ph3P–Br–Br ‘spoke’ structure and is isostructural with Ph3P–I–I and Ph3As–I–I; thus forcing us to question the conventional belief that tertia

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::63a11ee89eef6d9bfccaf903fe67e8cd
https://doi.org/10.1039/c39920000355

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The structure of triphenylphosphorus–diiodine, Ph3PI2, the first crystallographically characterised dihalogen derivative of a tertiary phosphine

Autor: Stephen M. Godfrey, Robin G. Pritchard, David G. Kelly, Charles A. McAuliffe, Susan M. Watson, Anthony G. Mackie

Publikováno v: J. Chem. Soc., Chem. Commun.. :1163-1164

Triphenylphosphine reacts with diiodine in dry diethyl ether to produce Ph3PI2, shown by X-ray crystallography to be a molecular four-coordinate compound Ph3P–I–I, and not the five-coordinate Ph3PI2 or the ionic [Ph3PI]+I–, previously thought t

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c9cbc24c39a957d482b876c6c0c3b298
https://doi.org/10.1039/c39910001163

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The use of the novel oxidising reagent triphenylarsine diiodine in the reaction with dicobalt octacarbonyl to produce a new type of complex [(Ph3Asl)2l][Co(AsPh3)l3]

Autor: Stephen M. Godfrey, Helen P. Lane, Anthony G. Mackie, Robin G. Pritchard, Charles A. McAuliffe

Publikováno v: Journal of the Chemical Society, Chemical Communications. :1190

Ph3AsI2 oxidises Co2(CO)8 in a 6 : 1 molar ratio to produce the novel complex [(Ph3AsI)2 I][Co(AsPh3)I3] in quantitative yield, the first crystallographically characterised complex containing a cobalt(II)-tertiary arsine bond and the unusual linear c

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f68a5c67d16d1be9ea2553cf6b90b24d
https://doi.org/10.1039/c39930001190

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