Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Anthony Cirri"'
Publikováno v:
The Journal of Physical Chemistry A. 124:1467-1479
Atomically precise gold nanoclusters (AuNCs) are a class of nanomaterials valued for their electronic properties and diverse structural features. While the advent of X-ray crystallography of AuNCs has revealed their geometric structures with high pre
Autor:
Jonathan W. Fagan, Christopher J. Johnson, K. L. Dimuthu M. Weerawardene, Anthony Cirri, Christine M. Aikens
Publikováno v:
The Journal of chemical physics. 155(1)
Ligand-protected gold nanoclusters (AuNCs) feature a dense but finite electronic structure that can be rationalized using qualitative descriptions such as the well-known superatomic model and predicted using quantum chemical calculations. However, th
Publikováno v:
Chemical Communications. 56:1283-1285
Recent experimental and computational results have suggested that a hydride bound to the Au9(PPh3)83+ gold nanocluster donates its electrons to the metal core, forming an 8-electron cluster. We present electronic absorption spectra of precisely mass-
Publikováno v:
Angewandte Chemie. 131:13956-13960
While the ability to crystallize metal nanoclusters has revealed their geometric structure, the lack of a similarly precise measure of their electronic structure has hampered the development of synthetic design rules to precisely engineer their elect
Autor:
Shelbie J. Cingoranelli, Karena W. Chapman, Brett A. Vaughn, C. Shaun Loveless, Shin Hye Ahn, Yi Yang, Suzanne E. Lapi, Eszter Boros, Christopher J. Johnson, Zhihengyu Chen, Anthony Cirri, Angus J Koller
Publikováno v:
Bioconjugate chemistry. 32(7)
The radioactive isotopes scandium-44/47 and lutetium-177 are gaining relevance for radioimaging and radiotherapy, resulting in a surge of studies on their coordination chemistry and subsequent applications. Although the trivalent ions of these elemen
Publikováno v:
Chemical communications (Cambridge, England). 56(8)
Recent experimental and computational results have suggested that a hydride bound to the Au9(PPh3)83+ gold nanocluster donates its electrons to the metal core, forming an 8-electron cluster. We present electronic absorption spectra of precisely mass-
Publikováno v:
The Journal of Physical Chemistry C. 122:11300-11304
CuFeO2 is an earth-abundant metal oxide semiconductor showing promising efficiency as a solar photocathode. Using extreme ultraviolet (XUV) and optical spectroscopy, we track the element-specific electron and hole dynamics in CuFeO2 and compare resul
Publikováno v:
The Journal of Physical Chemistry C. 121:15861-15869
Ultrafast extreme ultraviolet (XUV) spectroscopy is a powerful tool for probing electronic structure and charge carrier dynamics in catalytic materials because of its elemental, oxidation, coordination, and electronic spin-state sensitivity. To exten
Publikováno v:
Chemical Science. 8:8170-8178
Spectroscopically following charge carrier dynamics in catalytic materials has proven to be a difficult task due to the ultrafast timescales involved in charge trapping and the lack of spectroscopic tools available to selectively probe surface electr
Publikováno v:
Journal of the American Chemical Society. 138:15987-15993
Alkanethiolate protected gold nanoparticles are one of the most widely used systems in modern science and technology, where the emergent electronic properties of the gold core are valued for use in applications such as plasmonic solar cells, photocat