Zobrazeno 1 - 10
of 26
pro vyhledávání: '"Anne-Frédérique Pécharman"'
Autor:
Anne-Frédérique Pécharman, Annie L. Colebatch, Michael S. Hill, Claire L. McMullin, Mary F. Mahon, Catherine Weetman
Publikováno v:
Nature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
Organoboranes are widely employed in organic synthesis and typically are prepared using electrophilic boron sources. Here the authors report a route to nucleophilic boryl anions via organomagnesium-driven cleavage of boron-boron bonds.
Externí odkaz:
https://doaj.org/article/e8659eb09b804bfb9bf50536728eb2fe
Autor:
Connie J. Isaac, Fedor M. Miloserdov, Anne-Frédérique Pécharman, John P. Lowe, Claire L. McMullin, Michael K. Whittlesey
Publikováno v:
Organometallics. 41:2716-2730
Publikováno v:
Polar Organometallic Reagents. :97-131
Autor:
Lia Sotorríos, Mary F. Mahon, Nasir A. Rajabi, Anne-Frédérique Pécharman, Michael K. Whittlesey, Stuart MacGregor, John P. Lowe, Fedor M. Miloserdov
Publikováno v:
Inorganic Chemistry 60 (2021) 21
Inorganic Chemistry, 60(21), 16256-16265
Inorganic Chemistry, 60(21), 16256-16265
A combined experimental and computational study of the structure and reactivity of two [RuZn2Me2] complexes, neutral [Ru(PPh3)(Ph2PC6H4)2(ZnMe)2] (2) and cationic [Ru(PPh3)2(Ph2PC6H4)(ZnMe)2][BArF4] ([BArF4] = [B{3,5-(CF3)2C6H3}4]) (3), is presented.
Autor:
Lia Sotorrios, Fedor M. Miloserdov, Anne‐Frédérique Pécharman, John P. Lowe, Stuart A. Macgregor, Mary F. Mahon, Michael K. Whittlesey
Publikováno v:
Angewandte Chemie-International Edition 61 (2022) 19
Angewandte Chemie-International Edition, 61(19)
Angewandte Chemie-International Edition, 61(19)
The syntheses, reactivity and electronic structure analyses of [Ru(PPh3)2(ZnMe)4H2], 1 a, and [Ru(PPh3)2(ZnPh)4H2], 2 b, are reported. 1 a exhibits an 8-coordinate Ru centre with axial phosphines and a symmetrical (2 : 2) arrangement of ZnMe ligands
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0beb6d9d4c710d0c4a0c5c5e05f88f1b
https://research.wur.nl/en/publications/zinc-promoted-znmeznph-exchange-in-eight-coordinate-rupphsub3subs
https://research.wur.nl/en/publications/zinc-promoted-znmeznph-exchange-in-eight-coordinate-rupphsub3subs
Autor:
Lia, Sotorrios, Fedor M, Miloserdov, Anne-Frédérique, Pécharman, John P, Lowe, Stuart A, Macgregor, Mary F, Mahon, Michael K, Whittlesey
Publikováno v:
Angewandte Chemie (International ed. in English). 61(19)
The syntheses, reactivity and electronic structure analyses of [Ru(PPh
Autor:
Fedor M, Miloserdov, Anne-Frédérique, Pécharman, Lia, Sotorrios, Nasir A, Rajabi, John P, Lowe, Stuart A, Macgregor, Mary F, Mahon, Michael K, Whittlesey
Publikováno v:
Inorganic Chemistry
A combined experimental and computational study of the structure and reactivity of two [RuZn2Me2] complexes, neutral [Ru(PPh3)(Ph2PC6H4)2(ZnMe)2] (2) and cationic [Ru(PPh3)2(Ph2PC6H4)(ZnMe)2][BArF4] ([BArF4] = [B{3,5-(CF3)2C6H3}4]) (3), is presented.
Autor:
Nasir A. Rajabi, Anne-Frédérique Pécharman, Mary F. Mahon, Claire L. McMullin, Michael S. Hill
Publikováno v:
Chemical Communications. 55:9035-9038
Reaction of a magnesium diboranate complex with triphenylphosphine oxide provides a terminal magnesium boryl, which is itself a potent reagent for the deoxygenative reduction of Ph3PO. Computational analysis with density functional theory (DFT) indic
Autor:
Claire L. McMullin, Mary F. Mahon, Grace McMullon, Anne-Frédérique Pécharman, Michael S. Hill
Publikováno v:
Chemical Science. 10:6672-6682
Reactions of the β-diketiminato magnesium diboranate derivative, [(BDI)Mg{pinB(n-Bu)Bpin}] (BDI = HC{(Me)CNDipp}2; Dipp = 2,6-i-Pr2C6H3), with N,N′-dialkyl and N,N′-diaryl carbodiimides provided the corresponding C-borylated magnesium borylamidi
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 50(4)
A series of complexes generated through reactions of the β-diketiminato magnesium diboranate species, [(BDI)Mg{(n-Bu)pinB-Bpin}] (BDI = HC{(Me)CNDipp}2; Dipp = 2,6-di-iso-propylphenyl), and a variety of organic nitriles are reported. Although, in ev