Zobrazeno 1 - 10
of 149
pro vyhledávání: '"Anne Buyle Padias"'
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 50:3467-3474
The synthesis and polymerizability of imine CN monomers is surveyed. The investigated imines were either far more reactive than similarly substituted CC or CO monomers, or too stable to polymerize. Imines with electron-attracting substituents on N fa
Autor:
Anne Buyle Padias, Henry K. Hall
Publikováno v:
Polymers, Vol 3, Iss 2, Pp 833-845 (2011)
Polymers; Volume 3; Issue 2; Pages: 833-845
Polymers; Volume 3; Issue 2; Pages: 833-845
The LCP (Liquid Crystal Polymer) known as Vectra is synthesized by acidolysis of 4-hydroxybenzoic acid with 6-hydroxy-2-naphthoic acid. The apparently simple acidolysis mechanism for LCP polycondensation is in fact a complex blend of mechanisms. Kine
Autor:
H. K. Hall, Anne Buyle Padias
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 47:6735-6749
In spontaneous vinyl and ring-opening copolymer- izations, polar and resonance effects on the intermediates from bond- forming initiation offer a continu- ous spectrum of reactivities and polymer structures. In bond-form- ing initiation, an electron-
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 45:4751-4763
To obtain polyanilines which are more structurally perfect than those obtainable by the oxidation of anilines, polycondensation procedures were investigated. Model reactions gave extensive information about yields and about the physical properties of
Autor:
Anne Buyle Padias, H. K. Hall, El Hadj Elandaloussi, Árpád Somogyi, Douglas E. Hall, Robert B. Bates
Publikováno v:
Macromolecules. 40:5311-5321
The starting premise of this work was that matrices containing powerfully solvating groups would enhance the quality of MALDI-TOF spectra of condensation polymers. The solvating groups in these matrices would pry the polymer aggregates apart and make
Publikováno v:
Macromolecules. 39:6913-6923
To aid in the detailed characterization of the LCP polymer Vectra A950, 20 alternating dimers and 10 alternating tetrameric model oligomers were synthesized and subjected to detailed MALDI and ESI spectral characterization. The model compounds were s
Publikováno v:
Polymer Journal. 37:439-448
Anionic polymerization of methyl bicyclobutane-1-carboxylate (MBCB) with tert-butyllithium (t-BuLi)/bis(2,6-di-tert-butylphenoxy)ethylaluminum [EtAl(ODBP)2] in toluene at −78 °C gives transtactic polymers (trans contents > 90%) with high yields, b
Autor:
Henry K. Hall, Anne Buyle Padias
Publikováno v:
Helvetica Chimica Acta. 88:1553-1559
The zwitterionic–biradical tetramethylene proposed by Huisgen as the key intermediate in stepwise [2+2] cycloaddition reactions has been shown to be the crucial intermediate in spontaneous vinyl polymerizations as well. Predominantly biradical tetr
Publikováno v:
Helvetica Chimica Acta. 88:1397-1404
Bifunctional vinyl ethers react with electron-poor alkenes to cyclobutanes in good yields. The second CC bond reacted with neither the cyclobutane nor its zwitterion intermediate, even on heating. Cyclobutanes formed from ‘tetracyanoethylene’ (8)
Publikováno v:
Macromolecules. 38:4067-4071
Vectra, a commercial copolymer of 4-hydroxybenzoic acid (HBA) and 6-hydroxy-2-naphthoic acid (HNA), is highly intractable, and its analysis has always been problematic. Lower molecular weight polym...