Zobrazeno 1 - 10
of 33
pro vyhledávání: '"Anke Flemming"'
Synthesis and Molecular Structure of tert-Butyl 4-(2-tert-butoxy-2-oxoethyl)piperazine-1-carboxylate
Publikováno v:
Crystals, Vol 2, Iss 1, Pp 90-95 (2012)
The crystal and molecular structure of tert-butyl 4-(2-tert-butoxy-2-oxoethyl)-piperazine-1-carboxylate is reported. The title compound crystallizes from a petroleum ether/ethyl acetate mixture in the monoclinic space group P 21/c with four molecules
Externí odkaz:
https://doaj.org/article/f877b4ce8d7449bea1b0a96623a10616
Publikováno v:
Acta Crystallographica Section E, Vol 70, Iss 12, Pp o1288-o1289 (2014)
The title compound, C26H21O3P, was obtained as by-product due to the hydrolysis of the desired tosylated compound. The dihedral angles between the three aromatic rings attached to the P atom lie in the range 78.1 (1)–87.6 (1)°. The hydroxymethyl g
Externí odkaz:
https://doaj.org/article/fa7bbcea58b748f99e59ede461b32e60
Autor:
Dieter Schinzer, Andreas Seidel-Morgenstern, Martin Köckerling, Arne Bernsdorf, Anke Flemming, Oliver Boehm, Jan von Langermann, Heike Lorenz
Publikováno v:
Acta Crystallographica Section E, Vol 66, Iss 3, Pp o570-o570 (2010)
In the racemic title compound, C22H23NO7, the dihedral angle between the fused ring systems is 51.87 (6)°. Two of the methoxy groups are disordered over two orientations in 0.688 (5):0.312 (5) and 0.672 (15):0.328 (15) ratios. In the crystal, weak C
Externí odkaz:
https://doaj.org/article/27d2b7b6714f490fa6cee4fb4d15242e
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 639:2527-2531
The study is focused on the preparation, characterization, and structure elucidation of two new molecular cluster complexes of niobium, one with an aromatic N donor ligand, the other one with an O-carboxamide ligand: [Nb6Cl12(Pyr)6][AlCl4]2 (1) (Pyr
Publikováno v:
Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences 65(2010), 1128-1136
act as bioorthogonal conjugation partners in this ligation. To obtain such phosphanes, building blocks with good leaving groups for the introduction of radiofluorine or for the insertion of other labels and a coupling position for the azide moiety ar
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 636:562-568
The reaction of K[B(CN)4] with [Ph4P]Cl, [nBu4P]Br, [nBuPh3P]Br, or [EtPh3P]Cl (Ph = phenyl, nBu = n-butyl, Et = ethyl) affords [Ph4P][B(CN)4] (1), [nBu4P][B(CN)4] (2), [EtPh3P][B(CN)4] (3), and [nBuPh3P][B(CN)4] (4) in high yields. The structures of
Autor:
Martin Köckerling, Anke Flemming
Publikováno v:
Angewandte Chemie International Edition. 48:2605-2608
Complete exchange: [M(6)X(12)] type cluster compounds with an octahedral M(6) metal atom arrangement, which is completely surrounded by alcoholato ligands, were unknown until now. The first representatives are prepared containing a [Nb(6)(OR)(12)](4+
Autor:
Martin Köckerling, Anke Flemming
Publikováno v:
Angewandte Chemie. 121:2643-2646
Kompletter Ligandenaustausch: Clusterverbindungen vom [M6X12]-Typ mit einem oktaedrischen M6-Metallatomgerust, das vollstandig von Alkoholatoliganden umgeben ist, waren bisher unbekannt. Hier werden die ersten Vertreter mit [Nb6(OR)12]4+-Einheit (R=C
Publikováno v:
Journal of Cluster Science. 20:113-131
The syntheses and structures of [K(18-crown-6)]2[K(18-crown-6)(H2O)2]2[Nb6Cl12(CN)6] · 2CH3CN (1) and [(C6H5)4P]4[Nb6Cl12(NCS)6] · 0.94CH3OH (2), determined by X-ray single crystal diffraction, are reported. Crystal data: [K(18-crown-6)]2[K(18-crow
Publikováno v:
Journal of Solid State Chemistry. 181:2660-2665
Slow crystallization of (PyrH)2[Nb6Cl18] from hot ethanol solution affords triclinic (PyrH)2[Nb6Cl18]·EtOH. Treatment of [Nb6Cl14(H2O)4]·4H2O with pyridine in a methanol solution gives the second title compound, the cubic modification of (PyrH)2[Nb