Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Angela M. T. S. Domingos"'
Autor:
Carlos C. Romão, Maria Teresa Duarte, M.A.A.F. de C.T. Carrondo, Angela M. T. S. Domingos, M.H. Garcia, Maria José Calhorda, Alberto R. Dias
Publikováno v:
Journal of Organometallic Chemistry. 320:63-81
New complexes of the type [MCp2X(NCR)][PF6] (M = Mo, W; X = SR, halides; R = Me, Et, Ph) have been prepared from [MCp2X2] and TlPF6, NOPF6 or [FeCp2][PF6], in nitrile solvents. Some reactions of these cations with nucleophiles [L] have been studied.
Publikováno v:
Journal of Organometallic Chemistry. 289:377-383
Crystals of trans -{ReCl[CN(t-C 4 H 9 )](Ph 2 PCH 2 CH 2 PPh 2 ) 2 } · C 4 H 8 O solvate are monoclinic, space group P 2 1 / n , a 24.098(7), b 16.558(5), c 13.402(4) A, β 90.97(3)°, V 5346.82 A 3 at 25°C. F (000)= 2392, Z = 4, λ(Cu-K α 1.5418
Autor:
Clementina Teixeira, José A. Martinho Simões, Maria Arménia Carrondo, Alberto R. Dias, Angela M. T. S. Domingos, Maria José Calhorda
Publikováno v:
Organometallics. 5:660-667
Le compose du titre cristallise dans le systeme orthorhombique groupe d'espace Cmcm et sa structure est affinee jusqu'a R=0,0251. La methode Huckel generalisee montre que la rigidite de la geometrie de SO 4 est responsable de la petitesse de l'angle