Zobrazeno 1 - 10
of 46
pro vyhledávání: '"Andrzej S. Baranski"'
Autor:
Aliaksei Boika, Andrzej S. Baranski
Publikováno v:
Analytical Chemistry. 84:1353-1359
Ultrahigh frequency voltammetry involves low scan rate voltammetric measurements with microelectrodes polarized by high-frequency large-amplitude alternating potential. The method provides a simple means for studying electrothermal and dielectrophore
Autor:
Aliaksei Boika, Andrzej S. Baranski
Publikováno v:
Electrochimica Acta. 56:7288-7297
In this paper we describe numerical simulations of a number of physico-chemical phenomena observed at disk microelectrodes polarized with a high frequency ac waveform. These phenomena include resistive heating of an electrolyte solution surrounding a
Autor:
Aliaksei Boika, Andrzej S. Baranski
Publikováno v:
Analytical Chemistry. 82:8137-8145
We examined the effect of a large-amplitude high-frequency alternating potential modulation on direct currents associated with irreversible, quasi-reversible, and reversible electron-transfer processes occurring at microelectrodes under voltammetric
Autor:
Aliaksei Boika, Andrzej S. Baranski
Publikováno v:
Analytical Chemistry. 80:7392-7400
When a disk microelectrode is polarized with an alternating potential of very high frequency (0.1-2 GHz) and a high amplitude (up to 2.8 V rms), the electrode is heated up, and at the same time, a very intense electric field is created around the ele
Publikováno v:
Electrochimica Acta. 52:854-862
A relationship between the tip response and the tip-to-substrate separation distance was investigated under alternating current scanning electrochemical microscopy (AC-SECM) conditions. For insulating substrates only negative AC feedback was observed
Publikováno v:
Analytical Chemistry. 78:6747-6755
Cyclic chronopotentiometry provides a very simple detection method, which may be particularly useful in capillary electrophoresis (CE) and microseparation systems. It has been shown that for disk microelectrodes it is possible to define safe reductio
Publikováno v:
Journal of Electroanalytical Chemistry. 463:200-211
Convolutive voltammetry was employed in studies of the kinetics of sulfide ion adsorption at copper amalgam and mercury electrodes. Measurements were carried out for low electrode coverages to minimize the effect of the lateral interaction energy, an
Autor:
Krzysztof Winkler, Andrzej S. Baranski
Publikováno v:
Journal of Electroanalytical Chemistry. 453:29-38
Oxidation of ferrocene (Fc) and reduction of p-dicyanobenzene (DCB) were examined by ac-voltammetry in benzene solutions containing tetra-n-hexylammonium perchlorate at a hemispherical (Hg) and a disk (Au) μm-electrode, respectively. The specific co
Publikováno v:
Analytical Chemistry. 70:2895-2901
A method for studying impedance spectroscopy of micrometer-sized electrodes in the frequency range from 5 kHz to 5 MHz has been developed and tested. Details of the electronic circuit and the data processing method are provided. Since the method invo
Publikováno v:
Journal of Chromatography A. 811:181-192
A number of experimental approaches that should offer improved S/N in electrochemical detection were evaluated and compared. In addition, to evaluate and optimize the electrochemical response behavior of analytes under actual CE conditions, an on-lin