Zobrazeno 1 - 10
of 82
pro vyhledávání: '"Andrzej Plonka"'
Autor:
Andrzej Plonka
Dynamical processes in which many timescales coexist are called dispersive. The rate coefficients for dispersive processes depend on time. In the case of a chemical reaction, the time dependence of the rate coefficient, k(t), termed the specific reac
Autor:
Ewa Szajdzinska-Pietek, Erwin Mayer, Justyna Staluszka, Andrzej Plonka, Andreas Hallbrucker, Ingrid Kohl
Publikováno v:
Radiation Physics and Chemistry. 67:247-250
Using X-band ESR spectroscopy we have studied radicals produced by g-irradiation at 77 K in hyperquenched glassy water (HGW) doped with thymine, 2 0 -deoxythymidyne, 2-deoxy-d-ribose, and the equimolar mixture of thymine and 2deoxy-d-ribose. In HGW m
Autor:
Andrzej Plonka, Ingrid Kohl, Andreas Hallbrucker, Ewa Szajdzinska-Pietek, Justyna Staluszka, Erwin Mayer
Publikováno v:
Research on Chemical Intermediates. 29:63-70
A dispersive model of radical accumulation in irradiated solids is discussed by the example of hexagonal ice (Ih) and cubic ice (Ic) obtained by annealing of hyperquenched glassy water at 160 K. The model assumes that radical production upon γ-irrad
Autor:
Andrzej Plonka
Publikováno v:
Annual Reports Section "C" (Physical Chemistry). 97:91-147
Autor:
Andrzej Plonka
Publikováno v:
Chemical Physics Letters. 328:124-128
The stretched exponential (SE) and the power law (PL), fitting equally well the disulfide recombination of a de-novo peptide, differ markedly in estimation of thiyl radical population. This leads to quite different lifetime distribution functions enc
Autor:
Andrzej Plonka
Publikováno v:
Progress in Reaction Kinetics and Mechanism. 25:109-217
In general, chemical reactions proceeding on time scales comparable to, or shorter than, those of internal rearrangements in a reaction system renewing the environment of the reactants (mixing), are dispersive. For dispersive kinetics, as for dispers
Autor:
Andrzej Plonka
Publikováno v:
Journal of Molecular Liquids. 86:3-12
Some of the recent developments in dispersive kinetics are highlighted. Special attention is paid to renormalization of rate coefficients following from the stochastic theory of renewals (structural relaxations) in the reaction system.
Autor:
Andrzej Plonka
Publikováno v:
The Journal of Physical Chemistry B. 104:3804-3807
Most of low-temperature reactions proceed faster than would be predicted by an Arrhenius-type extrapolation from the high-temperature regions. The definitions of low- and high-temperature regions a...
Publikováno v:
Physical Chemistry Chemical Physics. 2:1587-1593
The effects of γ-irradiating three metastable forms of water at 77 K have been studied by electron spin resonance spectroscopy and are compared with those of hexagonal ice. Two amorphous forms of water were made by so-called hyperquenching of liquid
Publikováno v:
Macromolecules. 32:7454-7460
Aqueous solutions of Nafion, an ionomer consisting of a perfluorinated backbone and pendant sulfonic groups, were studied by the electron spin resonance (ESR) spin probe method and by fluorescence spectroscopy. The spin probes used were 4-(N,N-dimeth