Zobrazeno 1 - 10
of 260
pro vyhledávání: '"Andrzej L. Sobolewski"'
Publikováno v:
Molecules, Vol 26, Iss 17, p 5140 (2021)
The excited-state intramolecular proton transfer (ESIPT) phenomenon is nowadays widely acknowledged to play a crucial role in many photobiological and photochemical processes. It is an extremely fast transformation, often taking place at sub-100 fs t
Externí odkaz:
https://doaj.org/article/c6b9f15889754e048e0a5f8335602a1c
Autor:
Maciej Krzeszewski, Łukasz Dobrzycki, Andrzej L. Sobolewski, Michał K. Cyrański, Daniel T. Gryko
Publikováno v:
Chemical Science. 14:2353-2360
Saddle-shaped nanographene encompassing a pyrrolopyrrole core possesses an unusual propensity to oxidize (EHOMO = −4.44 eV) while being stable at ambient conditions.
Autor:
Andrzej L. Sobolewski, Wolfgang Domcke
The inversion of the energies of the lowest singlet (S1) and triplet (T1) excited states in violation of Hund’s multiplicity rule is a rare phenomenon in stable organic molecules. S1-T1 inversion has significant consequences for the photophysics an
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d36ab6aa3cf6efb1663559d5f66eac38
https://doi.org/10.26434/chemrxiv-2023-chzq3
https://doi.org/10.26434/chemrxiv-2023-chzq3
Publikováno v:
ChemPhysChem. 23
Autor:
Wolfgang Domcke, Andrzej L. Sobolewski
Publikováno v:
The journal of physical chemistry. B. 126(15)
In this perspective, we discuss a novel water-splitting scenario, namely the direct oxidation of water molecules by organic photooxidants in hydrogen-bonded chromophore-water complexes. In comparison with the established scenario of semiconductor-bas
Autor:
Bartłomiej Sadowski, Dominik Mierzwa, Seongsoo Kang, Marek Grzybowski, Yevgen M. Poronik, Andrzej L. Sobolewski, Dongho Kim, Daniel T. Gryko
Publikováno v:
Chemical communications (Cambridge, England). 58(22)
This communication describes the photophysical behavior of three analogs of cyclophane bearing the dipyrrolonaphthyridinedione (DPND) core. In these molecules, intersystem crossing (ISC) can be successfully induced by distinct changes in the deviatio
Autor:
Andrzej L. Sobolewski, Wolfgang Domcke, Emily J. Rabe, Xiang Huang, Cody W. Schlenker, Kathryn L. Corp, Johannes Ehrmaier
Publikováno v:
The Journal of Physical Chemistry A. 124:3698-3710
Recently, a derivative of the heptazine (tris-triazine) molecule, trianisole-heptazine (TAHz), was synthesized and was shown to catalyze the oxidation of water to hydroxyl radicals under 365 nm LED light in a homogeneous reaction (E. J. Rabe et al.,
Autor:
Andrzej L. Sobolewski, Wolfgang Domcke, Johannes Ehrmaier, Emily J. Rabe, Kathryn L. Corp, Xiang Huang, Mitchell E. Kaiser, Cody W. Schlenker
Publikováno v:
The Journal of Physical Chemistry C. 124:9151-9160
We demonstrate chemical tuning and laser-driven control of intermolecular H atom abstraction from protic solvent molecules. Using multipulse ultrafast pump-push-probe transient absorption (TA) spec...
Publikováno v:
Physical Chemistry Chemical Physics. 22:15437-15447
Photophysics of hexaazatrinaphthylene (HATN) in solution and in the solid state is determined by the nπ* character of its lowest excited singlet state and by the ππ* character of the first triplet state. The relaxation of an electronically excited
Autor:
Andrzej L. Sobolewski, Marzena Banasiewicz, Kinga Suwińska, Cristina A. Barboza, Pawel Gawrys
Publikováno v:
Physical Chemistry Chemical Physics. 22:6698-6705
A series of different electron-deficient aromatic substituents were used to investigate the role of the electron-acceptor strength on the photophysical properties of salicylaldimine derivatives. These molecules were synthesised and characterised thro