Cyclohexane oxidation: relationships of the process efficiency with electrical conductance, electronic and cyclic voltammetry spectra of the reaction mixture

Autor: Pawel Bloniarz, Andriy Zaborovsky, Jacques Muzart, Tomasz Paczeŝniak, Alexander Pokutsa, Dariya Maksym

Publikováno v: Reaction Kinetics, Mechanisms and Catalysis. 132:123-137

The cyclohexane oxidation by H2O2 using VO(acac)2 as starting catalyst in the presence of oxalic acid (OA) was studied. The dissociation of OA and VO(oxalate) formed in situ by interaction of VO(acac)2 with OA is the essence of the electrical conduct

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::774c0f87695c2137b017ff5df8683600
https://doi.org/10.1007/s11144-020-01913-6

Sustainable Oxidation of Cyclohexane and Toluene in the Presence of Affordable Catalysts: Impact of the Tandem of Promoter/Oxidant on Process Efficiency

Autor: Andriy Zaborovsky, Tomasz Paczeŝniak, Pawel Bloniarz, Sergiy Tkach, Alexander Pokutsa, Jacques Muzart

Publikováno v: ACS Omega, Vol 5, Iss 13, Pp 7613-7626 (2020)
ACS Omega
ACS Omega, ACS Publications, 2020, 5 (13), pp.7613-7626. ⟨10.1021/acsomega.0c00447⟩

International audience; The oxygenation of cyclohexane and toluene by O2 and H2O2 catalyzed by VO(acac)2 and Co(acac)2 was studied at 40–100 °C and 1–10 atm. Upon such conditions, the process can be remarkably (30× times) enhanced by the minute

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7a637a6d510101953d1edde3d1b27806
https://doaj.org/article/ce34d5f83e50408bac1233b8e245832c