Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Andrii Boretskyi"'
Autor:
Volodymyr Ahunovych, Anton A. Klipkov, Maksym Bugera, Karen Tarasenko, Serhii Trofymchuk, Oleh Stanko, Andrii Boretskyi, Mykola Zheludenko, Iryna V. Sadkova, Pavel K. Mykhailiuk
CF3-cyclopropanes were prepared on a multigram scale by deoxyfluorination of cyclopropane carboxylic acids or their salts with sulfur tetrafluoride. For labile α-pyridine acetic acids, only the use of salts allowed to obtain the needed products. Der
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1afe86480577cea86c94691b43b8d605
https://doi.org/10.26434/chemrxiv-2023-qp012
https://doi.org/10.26434/chemrxiv-2023-qp012
Autor:
H. V. Rasika Dias, Pavel K. Mykhailiuk, Anurag Noonikara-Poyil, Andrii Boretskyi, Alvaro Muñoz-Castro
Publikováno v:
Chemical Science
Polyfluorinated, electron-withdrawing, and sterically demanding supporting ligands are of significant value in chemistry. Here we report the assembly and use of a bis(pyrazolyl)borate, [Ph2B(3-(SF5)Pz)2]− that combines all such features, and involv
Autor:
Pavel K. Mykhailiuk, Volodymyr Ahunovych, Karen V. Tarasenko, Serhii A. Trofymchuk, Bohdan Razhyk, Sergey Semenov, Anton A. Klipkov, Maksym Ya. Bugera, Andrii Boretskyi
Publikováno v:
The Journal of Organic Chemistry. 86:12181-12198
A general approach to fluorinated (hetero)aromatic derivatives is elaborated. The key reaction is a deoxofluorination of substituted acetophenones with sulfur tetrafluoride (SF4). In contrast to previous deoxofluorination methods, this transformation