Structural diversity in the series of lanthanide complexes [Ln(Ph3PO)n(NCS)3] (n = 3, 4)

Autor: Lawrence Chan, Simon A. Cotton, Joanna Dickson (nee Harris), Andrew W.G. Platt, Paul R. Raithby, Stefanie Schiffers, Alexander Tait, John E. Warren

Publikováno v: Chan, L, Cotton, S A, Dickson (nee Harris), J, Platt, A W G, Raithby, P R, Schiffers, S, Tait, A & Warren, J E 2022, ' Structural diversity in the series of lanthanide complexes [Ln(Ph 3 PO) n (NCS) 3 ] (n = 3, 4) ', Polyhedron, vol. 220, 115826 . https://doi.org/10.1016/j.poly.2022.115826

Two unique series of lanthanide complexes [Ln(Ph3PO)4(NCS)3] (Ln = La-Tb, except Pm) and [Ln(Ph3PO)3(NCS)3] (Ln = Sm-Lu, Y) have been structurally characterised. The isomorphous series [Ln(Ph3PO)4(NCS)3] crystallises in the monoclinic centrosymmetric

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::df3bad47f01ae179e9d1872540ebd937
https://doi.org/10.1016/j.poly.2022.115826

Synthesis, Structural Characterisation and Solution Behaviour of High‐Symmetry Lanthanide Triflate Complexes with the Sterically Demanding Phosphine Oxides Cy 3 PO and t Bu 3 PO

Autor: Andrew W.G. Platt, Simon J. Coles, Mateusz B. Pitak

Publikováno v: European Journal of Inorganic Chemistry. 2017:1464-1471

The synthesis and characterisation of complexes formed from lanthanide trifluoromethanesulfonates [Ln(OTf)3] and tricyclohexylphosphine oxide (Cy3PO) or tri‐tert‐butylphosphine oxide (tBu3PO) are described. The structures of [Ln(H2O)5(Cy3PO)2]·2

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f28df135135044d969db3d8872b7dda3
https://doi.org/10.1002/ejic.201601471

Complexes of lanthanide chlorides with tricyclohexylphosphine oxide. The single crystal X-ray structures and solution properties of pentagonal bipyramidal complexes [Ln(H2O)5(Cy3PO)2]3+·Cy3PO·3Cl− Ln=Dy, Er

Autor: Anthony M.J. Lees, Andrew W.G. Platt

Publikováno v: Polyhedron

The products of the reactions of tricyclohexylphosphine oxide, Cy3PO = L, with lanthanide chlorides (Ln = La, Dy, Er, Yb) have been investigated by solution NMR spectroscopy and single crystal X-ray crystallography (Dy, Er). The structures of the com

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https://doi.org/10.1016/j.poly.2013.09.026

Lanthanide phosphine oxide complexes

Autor: Andrew W.G. Platt

Phosphine oxide complexes of lanthanide metal have been studied to elucidate the fundamental aspects\ud of their structural chemistry and to develop important technological applications mainly in the reprocessing\ud of nuclear fuels and in photolumin

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Complexes of Lanthanide Nitrates with Tri Tert Butylphosphine Oxide

Autor: Simon J. Coles, Allen Bowden, Mateusz B. Pitak, Andrew W.G. Platt

Publikováno v: Inorganic Chemistry. 51:4379-4389

Reaction of lanthanide nitrates with (t)Bu(3)PO (=L) lead to the isolation of complexes Ln(NO(3))(3)L(2)·H(2)O·nEtOH (Ln = La (1), Nd(2)), Ln(NO(3))(3)L(2) ·nEtOH (Sm(3), Eu(4)), and Ln(NO(3))(3)L(2) (Dy(5), Er(6), Lu(7)). These have been characte

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https://doi.org/10.1021/ic300142r