Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Andrew J. Duffield"'
Publikováno v:
Journal of Organometallic Chemistry. 175:293-302
The kinetics of the reactions of the manganese pentacarbonyl halides Mn(CO) 5 X, X = Cl, Br, or I, with cyanide to give the [Mn(CO) 4 (CN) 2 ] − anion are reported. The respective rate laws and rate constants indicate that the intermediate in their
Autor:
John Burgess, Andrew J. Duffield
Publikováno v:
Journal of Organometallic Chemistry. 177:435-442
Manganese pentacarbonyl bromide reacts with β-alanine to give manganese tricarbonyl bis-(β-alanine) bromide. The kinetics of this reaction are described, the first step under thermal and the second under photochemical conditions. Rate constants in
Autor:
John Burgess, Andrew J. Duffield
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 42:1531-1534
Publikováno v:
Transition Metal Chemistry. 6:368-371
Rate constants have been determined for the reaction of [PtCl4]2− with cyanide in water and in 20% and 40% (v/v) methanol, and for the reaction of [Pd(Et4dien)Cl]+ with thiourea in water, in 50% methanol, and in 50% DMSO, in all cases at 298.2K. Th
Publikováno v:
Transition Metal Chemistry. 2:276-277
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :350
Activation volumes for reactions of [Fe(4-Me-phen)3]2+ with cyanide and with peroxodisulphate, and of Mo(bipy)(CO)4 with cyanide in various solvents suggest that cyanide or peroxodisulphate desolvation is a dominant feature in transition state format
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :1
Solubilities of potassium cyanide in a variety of non-aqueous solvents and binary aqueous solvent mixtures are reported. From these results and from published data on Gibbs free energies of transfer of the potassium ion, Gibbs free energies have been