Zobrazeno 1 - 10
of 96
pro vyhledávání: '"Andrew J, Gaunt"'
Autor:
Justin C. Wedal, Jesse Murillo, Joseph W. Ziller, Brian L. Scott, Andrew J. Gaunt, William J. Evans
Publikováno v:
Inorganic Chemistry. 62:5897-5905
Autor:
Stephanie H. Carpenter, Bonnie E. Klamm, Taylor V. Fetrow, Brian L. Scott, Andrew J. Gaunt, Nickolas H. Anderson, Aaron M. Tondreau
Publikováno v:
Inorganic Chemistry.
Autor:
Michaela Černá, John A. Seed, Sara Garrido Fernandez, Michael T. Janicke, Brian L. Scott, George F. S. Whitehead, Andrew J. Gaunt, Conrad A. P. Goodwin
Publikováno v:
Chemical Communications. 58:13278-13281
A bis-phospholide framework allows isolation, structural, and spectroscopic characterisation of isostructural lanthanide, uranium, neptunium, and plutonium σ-bonded hydrocarbyl complexes.
Publikováno v:
Goodwin, C, Janicke, M T, Scott, B L & Gaunt, A 2021, ' [AnI3(THF)4] (An = Np, Pu) Preparation Bypassing An0 Metal Precursors: Access to Np3+/Pu3+ Nonaqueous and Organometallic Complexes ', Journal of the American Chemical Society, vol. 143, no. 49, pp. 20680-20696 . https://doi.org/10.1021/jacs.1c07967
Direct comparison of homologous molecules provides a foundation from which to elucidate both subtle and patent changes in reactivity patterns, redox processes, and bonding properties across a series of elements. While trivalent molecular U chemistry
Autor:
Conrad A. P. Goodwin, Anthony W. Schlimgen, Thomas E. Albrecht‐Schönzart, Enrique R. Batista, Andrew J. Gaunt, Michael T. Janicke, Stosh A. Kozimor, Brian L. Scott, Lauren M. Stevens, Frankie D. White, Ping Yang
Publikováno v:
Angewandte Chemie International Edition. 60:9459-9466
Covalency is often considered to be an influential factor in driving An3+ vs. Ln3+ selectivity invoked by soft donor ligands. This is intensely debated, particularly the extent to which An3+ /Ln3+ covalency differences prevail and manifest as the f-b
Autor:
Lauren M. Stevens, Guang Wu, Trevor W. Hayton, Brennan S. Billow, Brian L. Scott, Conrad A. P. Goodwin, Danil E. Smiles, Aaron M. Tondreau, Andrew J. Gaunt, Selena Staun
Publikováno v:
Inorganic Chemistry. 60:2740-2748
Reaction of 3 equiv of NaNR2 (R = SiMe3) with NpCl4(DME)2 in THF afforded the Np(IV) silylamide complex, [Np(NR2)3Cl] (1), in good yield. Reaction of 1 with 1.5 equiv of KC8 in THF, in the presence of 1 equiv of dibenzo-18-crown-6, resulted in format
Autor:
Michał S. Dutkiewicz, Conrad A. P. Goodwin, Mauro Perfetti, Andrew J. Gaunt, Jean-Christophe Griveau, Eric Colineau, Attila Kovács, Ashley J. Wooles, Roberto Caciuffo, Olaf Walter, Stephen T. Liddle
Publikováno v:
Dutkiewicz, M S, Goodwin, C, Perfetti, M, Gaunt, A J, Griveau, J-C, Colineau, E, Kovács, A, Wooles, A J, Caciuffo, R, Walter, O & Liddle, S T 2022, ' A Terminal Neptunium(V)-Mono(Oxo) Complex ', Nature Chemistry, vol. 14, no. 3, pp. 342-349 . https://doi.org/10.1038/s41557-021-00858-0
Neptunium was the first actinide element to be artificially synthesized, yet, compared with its more famous neighbours uranium and plutonium, is less conspicuously studied. Most neptunium chemistry involves the neptunyl di(oxo)-motif, and transuranic
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::60d08c379e1e8c6b368eefe4db759c3f
https://pure.manchester.ac.uk/ws/files/207569884/NpO_Paper_for_repository.pdf
https://pure.manchester.ac.uk/ws/files/207569884/NpO_Paper_for_repository.pdf
Autor:
Conrad A. P. Goodwin, Sierra R. Ciccone, Samuel Bekoe, Sourav Majumdar, Brian L. Scott, Joseph W. Ziller, Andrew J. Gaunt, Filipp Furche, William J. Evans
Publikováno v:
Chemical communications (Cambridge, England). 58(7)
The THF-soluble [An(crypt)(OTf)2][OTf] complexes for An = Np and Pu were synthesized from AnI3(THF)4 starting materials based on pilot studies of the An = U system. 5f3 U(iii), 5f4 Np(iii), and 5f5 Pu(iii) electron configurations are indicated by DFT
Autor:
William J. Evans, Conrad A. P. Goodwin, Joseph M. Sperling, Thomas E. Albrecht-Schönzart, Jing Su, Stosh A. Kozimor, Lauren M. Stevens, Justin C. Wedal, Ping Yang, Frankie D. White, Zachary R. Jones, Sasha F. Briscoe, Alyssa N. Gaiser, Cory J. Windorff, Enrique R. Batista, Andrew J. Gaunt, Joseph W. Ziller, Brian L. Scott, Nickolas H. Anderson, Michael R. James, John D. Auxier, Justin N. Cross, Tener F. Jenkins, Michael T. Janicke
Publikováno v:
Goodwin, C A P, Su, J, Stevens, L M, White, F D, Anderson, N H, Auxier, J D, Albrecht-Schönzart, T E, Batista, E R, Briscoe, S F, Cross, J N, Evans, W J, Gaiser, A N, Gaunt, A J, James, M R, Janicke, M T, Jenkins, T F, Jones, Z R, Kozimor, S A, Scott, B L, Sperling, J M, Wedal, J C, Windorff, C J, Yang, P & Ziller, J W 2021, ' Isolation and characterization of a californium metallocene ', Nature, vol. 599, 7885, pp. 421-424 . https://doi.org/10.1038/s41586-021-04027-8
Californium (Cf) is currently the heaviest element accessible above microgram quantities. Cf isotopes impose severe experimental challenges due to their scarcity and radiological hazards. Consequently, chemical secrets ranging from the accessibility
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e50199d4abf1dbf56d24d5404e1fcdc0
https://research.manchester.ac.uk/en/publications/e1598796-ae4f-4c98-8f2d-4b147e0323f6
https://research.manchester.ac.uk/en/publications/e1598796-ae4f-4c98-8f2d-4b147e0323f6
Autor:
Andrew J. Gaunt, Hadiqa Zafar, Douglas P. Saunders, Michael A. Boreen, Vincent M. Lynch, Conrad A. P. Goodwin, Mary E. Garner, James T. Brewster, Nicholas S. Settineri, John Arnold, Jonathan L. Sessler, Daniel N. Mangel
Publikováno v:
Journal of the American Chemical Society. 141:17867-17874
Here we report the first series of in-plane thorium(IV), uranium(IV), and neptunium(IV) expanded porphyrin complexes. These actinide (An) complexes were synthesized using a hexa-aza porphyrin analogue, termed dipyriamethyrin, and the nonaqueous An(IV