Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Andrew G Walden"'
Autor:
Ian L Peczak, Ryan. M. Davis, Megan Mohadjer Beromi, Amira H. Dardir, Hannah M. C. Lant, David Balcells, Brandon Q. Mercado, Gary W. Brudvig, Andrew G Walden, Nilay Hazari, Emily L Barth
Publikováno v:
Organometallics
Aryl carbonates, a common protecting group in synthetic organic chemistry, are potentially valuable electrophiles in cross-coupling reactions. Here, after performing a thorough evaluation of different precatalysts, we demonstrate that (dcypf)Ni(2-eth
Autor:
Andrew G. Walden, Nicholas Lease, Andrea Casuras, Brian M. Lindley, Chun-Hsing Chen, Ann Marie Brasacchio, Alexander J. M. Miller, Alan S. Goldman
Publikováno v:
Chemical Science. 10:9326-9330
A C–H bond activation strategy based on electrochemical activation of a metal hydride is introduced. Electrochemical oxidation of (tBu4PCP)IrH4 (tBu4PCP is [1,3-(tBu2PCH2)-C6H3]−) in the presence of pyridine derivatives generates cationic Ir hydr
Publikováno v:
Dalton Transactions. 45:9766-9769
With a view towards replacing sacrificial hydrogen acceptors in alkane dehydrogenation catalysis, electrochemical methods for oxidative activation of a pincer-ligated iridium hydride intermediate were explored. A 1H(+)/2e(-) oxidation process was obs
Publikováno v:
Journal of the American Chemical Society. 136:14718-14721
Visible light-triggered hydride transfer from [Cp*Ir(bpy)(H)](+) (1) to organic acids and 1-methylnicotinamide (MNA(+)) is reported (Cp* = pentamethylcyclopentadienyl; bpy = 2,2'-bipyridine). A new thermochemical cycle for determining excited-state h
Publikováno v:
Chemical Science
A ruthenium complex of the tripodal ligand tris(2-pyridyl)phosphine oxide exhibits rapid water oxidation electrocatalysis over a wide pH range.
The tris(2-pyridyl)phosphine oxide (Py3PO) complex [Ru(Py3PO)(bpy)(OH2)]2+ (bpy is 2,2′-bipyridine)
The tris(2-pyridyl)phosphine oxide (Py3PO) complex [Ru(Py3PO)(bpy)(OH2)]2+ (bpy is 2,2′-bipyridine)