Zobrazeno 1 - 10
of 61
pro vyhledávání: '"Andrew E, Ashley"'
Autor:
Alexandros Paparakis, Roland C. Turnell-Ritson, Joshua S. Sapsford, Andrew E. Ashley, Martin Hulla
Publikováno v:
Catalysis Science & Technology. 13:637-644
Tin-based FLPs catalyze reductive coupling reactions of amines with CO2 and H2. Water produced by the reaction is well tolerated and TONs up to 300 can be achieved.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c40cb55e36dfd3a102d32716dd7b5323
https://doi.org/10.1039/d2cy01659a
https://doi.org/10.1039/d2cy01659a
Autor:
Roland C. Turnell-Ritson, Adam D. Piascik, Joshua S. Sapsford, Daniel J. Scott, Dániel Csókás, Imre Pápai, Andrew E. Ashley
Publikováno v:
ACS Catalysis
Cationic Lewis acids (LAs) are gaining interest as targets for frustrated Lewis pair (FLP)-mediated catalysis. Unlike neutral boranes, which are the most prevalent LAs for FLP hydrogenations, the Lewis acidity of cations can be tuned through modulati
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::eecddb43cea039d58b123f2310e85b61
http://europepmc.org/articles/PMC7469243
http://europepmc.org/articles/PMC7469243
Autor:
Andrew D. Crawford, Liam A. Parkin, Joshua S. Sapsford, Andrew E. Ashley, Imre Pápai, Dániel Csókás, Roland C. Turnell-Ritson
‘Frustrated Lewis pairs’ (FLPs) continue to exhibit unique reactivity for the reduction of organic substrates, yet to date the catalytic hydrogenation of an ester functionality has not been demonstrated. Here we report that iPr3SnNTf2 (1-NTf2; Tf
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d90f58a8464074ef18633b692efabd46
http://hdl.handle.net/10044/1/90177
http://hdl.handle.net/10044/1/90177
Publikováno v:
Journal of the American Chemical Society. 140:10691-10694
The catalytic conversion of N2 to N(SiMe3)3 by homogenous transition metal compounds is a rapidly developing field, yet few mechanistic details have been experimentally elucidated for 3d element catalysts. Herein we show that Fe(PP)2(N2) (PP = R2PCH2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7170e4024dd56b47daa00bf99dc7c564
https://doi.org/10.1021/jacs.8b06999
https://doi.org/10.1021/jacs.8b06999
Autor:
Gregory G. Wildgoose, Daniel J. Scott, Elliot J. Lawrence, J. Chris Slootweg, Joshua S. Sapsford, Fraser MacMillan, Elliot L. Bennett, Andrew E. Ashley, Andreas W. Ehlers, Anna Mullen, Robin J. Blagg
Publikováno v:
Angewandte Chemie, International Edition, 58(25), 8362-8366. John Wiley and Sons Ltd
Angewandte Chemie, 131(25), 8450-8454. John Wiley and Sons Ltd
Angewandte Chemie (International Ed. in English)
Angewandte Chemie, 131(25), 8450-8454. John Wiley and Sons Ltd
Angewandte Chemie (International Ed. in English)
We herein explore whether tris(aryl)borane Lewis acids are capable of cleaving H2 outside of the usual Lewis acid/base chemistry described by the concept of “frustrated Lewis pairs” (FLPs). Instead of a Lewis base we use a chemical reductant to g
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bbc3c92d130a26834f2d58ddf8a7e979
https://doi.org/10.1002/ange.201900861
https://doi.org/10.1002/ange.201900861
Autor:
Andrew E. Ashley, Adam D. Piascik
Publikováno v:
Transition Metal-Dinitrogen Complexes
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7c80e777ce4c5e10ac5a1af3b00e481e
https://doi.org/10.1002/9783527344260.ch6
https://doi.org/10.1002/9783527344260.ch6
Autor:
Andrew E. Ashley, Laurence R. Doyle, Joshua S. Sapsford, Russell A. Taylor, Silvia Díez-González, Sarah J. Gates
Publikováno v:
Inorganica chimica acta, 2019, Vol.488, pp.201-207 [Peer Reviewed Journal]
[Cp*Fe(Me2PCH2CH2PMe2)(CO)]+ [BArF24]− has been synthesised and characterised using single crystal X-ray diffraction, NMR and IR spectroscopies. Reduction of the CO ligand using Na[Et3BH] produces the corresponding neutral formyl complex Cp*Fe(Me2P
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0f0ba86b969366e475d4247b4586ba0e
http://hdl.handle.net/10044/1/67863
http://hdl.handle.net/10044/1/67863
Autor:
Daniel J. Scott, Andrew J. P. White, Peter J. Hill, Duncan A. X. Fraser, William K. Myers, Jennifer C. Green, Laurence R. Doyle, Andrew E. Ashley
The synthesis and characterisation of the S = 1/2 Fe(I) complex [Fe(depe)2]+[BArF4]− ([1]+[BArF4]−), and the facile reversible binding of N2 and H2 in both solution and the solid state to form the adducts [1·N2]+ and [1·H2]+, are reported. Coor
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::48d05bcca2f7e9ee61bea763e323a2a9
https://ora.ox.ac.uk/objects/uuid:38f23d00-fe09-4358-8e4f-84f0c8f1360b
https://ora.ox.ac.uk/objects/uuid:38f23d00-fe09-4358-8e4f-84f0c8f1360b
Autor:
Roland C. Turnell-Ritson, Andrew E. Ashley, Tamás Földes, Robert Cooper, Stella S. Lee, Imre Pápai, Joshua S. Sapsford, Patricia A. Hunt
A range of amines catalyse the oxidative addition (OA) of H2 to [(Me3Si)2CH]2Sn (1), forming [(Me3Si)2CH]2SnH2 (2). Experimental and computational studies point to ‘frustrated Lewis pair’ mechanisms in which 1 acts as a Lewis acid and involve unu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ab8e39cb03e0f9bb6b7866d805ac7c08
http://hdl.handle.net/10044/1/65377
http://hdl.handle.net/10044/1/65377
Publikováno v:
Journal of the American Chemical Society. 140(34)
The catalytic conversion of N
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::c3943ff6aa3470b0419782a3ac253239
https://pubmed.ncbi.nlm.nih.gov/30114921
https://pubmed.ncbi.nlm.nih.gov/30114921