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One-Electron Reduction of Molybdenum η2(4e)-Alkyne Complexes as a Pathway to the η2(3e) Vinyl Ligand
Autor:
Adrian C. Whitwood, Deborah C. Spinks, Sarah Baines, Andrew R. Chafen, Michael J. Cowley, Jason M. Lynam
Publikováno v:
Organometallics. 26:1093-1095
Reaction of the molybdenum alkyne complex [Mo(P{OMe}3)2(η2{4e}-PhC2Ph)(η5-C5H5)][BF4] with K[Fe(CO)2(η5-C5H5)] results in the formation of the η2(3e)-vinyl complex and [Fe(CO)2(η5-C5H5)]2. A study ...
Autor:
Sarah Baines, Michael J. Cowley, Andrew R. Chafen, Jason M. Lynam, Deborah C. Spinks, Adrian C. Whitwood
Publikováno v:
Organometallics; Feb2007, Vol. 26 Issue 4, p1093-1095, 3p