Zobrazeno 1 - 10
of 262
pro vyhledávání: '"Andreja Bakac"'
Autor:
Theresa L. Windus, Oleg Pestovsky, Kathleen E. Kristian, Emily A. Hull, Andreja Bakac, Aaron C. West, James Francis Dunne, Arkady Ellern, Jack M. Carraher
Publikováno v:
Dalton Transactions. 44:3811-3816
Transition metal complexes (NH3)5CoX(2+) (X = CH3, Cl) and L(H2O)MX(2+), where M = Rh or Co, X = CH3, NO, or Cl, and L is a macrocyclic N4 ligand are examined by both experiment and computation to better understand their electronic spectra and associ
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9d05b65a9b0df6c60696914404a75188
https://doi.org/10.1039/c4dt03143a
https://doi.org/10.1039/c4dt03143a
Publikováno v:
Inorganica Chimica Acta. 409:254-258
We found that the macrocyclic rhodium(II) complexes LRh(H2O)2+ (L = L1 = cyclam and L2 = meso-Me-6-cyclam) react with alkyl hydroperoxides RC(CH3)2OOH to generate the corresponding rhodium(III) alkyls L(H2O)RhR2+ (R = CH3, C2H5, PhCH2). Methyl and be
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bd46ea7a4f2abee336f7c5d442b665ef
https://doi.org/10.1016/j.ica.2013.09.022
https://doi.org/10.1016/j.ica.2013.09.022
Autor:
Andreja Bakac, Jack M. Carraher
Publikováno v:
Phys. Chem. Chem. Phys.. 16:19429-19436
Laser flash photolysis of 4-benzoylpyridine N-oxide (BPyO) at 308 nm in aqueous solutions generates a triplet excited state (3)BPyO* that absorbs strongly in the visible, λmax 490 and 380 nm. (3)BPyO* decays with the rate law kdecay/s(-1) = (3.3 ±
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::248a635b3dbfecc3fcb6933286f948e7
https://doi.org/10.1039/c4cp02751e
https://doi.org/10.1039/c4cp02751e
Publikováno v:
Inorganic chemistry. 55(13)
The kinetics of oxidation of organic and inorganic reductants by aqueous iron(IV) ions, Fe(IV)(H2O)5O(2+) (hereafter Fe(IV)aqO(2+)), are reported. The substrates examined include several water-soluble ferrocenes, hexachloroiridate(III), polypyridyl c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::76b2c7e30281148783ceef89e249cd75
https://pubmed.ncbi.nlm.nih.gov/27320290
https://pubmed.ncbi.nlm.nih.gov/27320290
Publikováno v:
The Journal of Physical Chemistry C. 116:10382-10389
Photochemical methods facilitate the generation, isolation, and study of metastable nanomaterials having unusual size, composition, and morphology. These harder-to-isolate and highly reactive phases, inaccessible using conventional high-temperature p
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::738baa6bca0e69704ebd97a26e55ca2c
https://doi.org/10.1021/jp301459s
https://doi.org/10.1021/jp301459s
Autor:
Kathleen E. Kristian, Andreja Bakac
Publikováno v:
Inorganic Chemistry. 51:4877-4882
Nitrous acid reacts with L(2)(H(2)O)Rh(2+) (L(2) = meso-hexamethylcyclam) in acidic aqueous solutions to generate a strongly absorbing intermediate Int-1 (λ(max) 400 nm, ε = 1200 M(-1) cm(-1)). The reaction follows a mixed second order rate law wit
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cd3f8d19d0a375b9c226009690ffa9e0
https://doi.org/10.1021/ic300597n
https://doi.org/10.1021/ic300597n
Publikováno v:
Chemistry – A European Journal. 17:4513-4517
The important roles that nitric oxide (NO) plays in biological environments, and the need for precise and targeted delivery of NO for medicinal and other purposes have led to intense research in the area of metal nitrosyl complexes as thermal and pho
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e2e6229cc2b70f1048e9957209cb5f64
https://doi.org/10.1002/chem.201003003
https://doi.org/10.1002/chem.201003003
Publikováno v:
Journal of Coordination Chemistry. 63:2578-2585
The reaction between aqueous manganese(III) ions, , and (H2O)5CrOO2+ has a 1 : 1 stoichiometry and generates and O2 as products. The mixed second-order rate constant exhibits an [H+] dependence that identifies the hexaaquamanganese ion as the reactiv
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::46ab19c0f427aaebc130ac24816c1ab0
https://doi.org/10.1080/00958972.2010.498510
https://doi.org/10.1080/00958972.2010.498510
Publikováno v:
Inorganic Chemistry. 49:7182-7187
The reaction between NO and L(2)(H(2)O)Rh(2+) (L(2) = meso-Me(6)-1,4,8,11-tetraazacyclotetradecane) generates a sky-blue L(2)(H(2)O)RhNO(2+), a {RhNO}(8) complex. The crystal structure of the perchlorate salt features a bent Rh-N-O moiety (122.1(11)(
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::376ecc73db231722355216fb2178779c
https://doi.org/10.1021/ic101236x
https://doi.org/10.1021/ic101236x
Autor:
Ewa Szajna-Fuller, Andreja Bakac
Publikováno v:
European Journal of Inorganic Chemistry. 2010:2488-2494
Hydrogen evolution from acidic aqueous solutions of TiIIIcitrate is strongly catalyzed by Co(dmgBF{sub 2}){sub 2}. The reaction generates an intermediate with maximum absorbance at 770 nm. The slow disappearance of this intermediate takes place simul
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::94066f468519c525e996ace519681ff5
https://doi.org/10.1002/ejic.200901176
https://doi.org/10.1002/ejic.200901176