Zobrazeno 1 - 2
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pro vyhledávání: '"Andrei Golushko"'
Publikováno v:
Chemical Science. 14:2983-2989
The use of epoxides as aldehyde surrogates allows isochromans to be constructed with greater scope than previously reported oxa-Pictet–Spengler reactions. The initial Meinwald rearrangement and subsequent steps are promoted by HFIP and triflic acid
Autor:
Andrei Golushko, Florent Noël, Shaofei Zhang, Marie Vayer, Nazanin Rezajooei, Christopher N. Rowley, Vuk D. Vuković, Joseph Moran, David Lebœuf
Publikováno v:
Chem
Chem, Cell Press, In press, ⟨10.1016/j.chempr.2021.10.023⟩
Chem, In press, ⟨10.1016/j.chempr.2021.10.023⟩
Chem, Cell Press, In press, ⟨10.1016/j.chempr.2021.10.023⟩
Chem, In press, ⟨10.1016/j.chempr.2021.10.023⟩
International audience; Alcohols and epoxides are arguably ideal electrophiles for the Friedel-Crafts alkylation, since they are widely available, require no pre-activation, and produce no stoichiometric waste beyond water. However, neither primary a