Zobrazeno 1 - 10 of 15 pro vyhledávání: '"Andreas Miska"'
3
Formation, Reactivity Tuning and Kinetic Investigations of Iron 'Dioxygen' Intermediate Complexes and Derivatives in Multiphase Flow Reactions
Autor: Siegfried Schindler, Andreas Miska, Pascal Specht, Markus Lerch
Publikováno v: Reactive Bubbly Flows ISBN: 9783030723606
A dinuclear iron complex system had been developed that is capable to activate dioxygen in the protic solvent methanol forming a peroxido complex that is stable for a few seconds at room temperature. A full kinetic analysis of this reaction could be
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e1b38c05cd2f702544238695e5ebfd60
https://doi.org/10.1007/978-3-030-72361-3_5
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5
Synthesis of an Iron(IV) Aqua-Oxido Complex Using Ozone as an Oxidant
Autor: Stefan Schaub, Doreen Mollenhauer, Stefan Zahn, Volker Schünemann, S. Sakshath, Andreas Miska, Jonathan Becker, Siegfried Schindler
Publikováno v: Angewandte Chemie. 130:5453-5456
The iron(IV) oxido complex [(tmc)Fe=O(OTf)]OTf with the macrocyclic ligand 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclo-tetradecane (tmc) has been synthesized using ozone as an oxidant. By adding water to this compound the complex [(H2 O)(tmc)Fe=O)](O
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::275f481432d6cce9b48f76bebb83a851
https://doi.org/10.1002/ange.201800475
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6
Dioxygen Activation: Potential Future Technical Applications in Reactive Bubbly Flows
Autor: Siegfried Schindler, Jonah Norbury, Andreas Miska, Markus Lerch
Publikováno v: Chemical Engineering & Technology. 40:1522-1526
A dinuclear iron complex reacts with dioxygen to form a peroxido complex which has the potential to be used in homogeneous catalysis for selective oxidation of organic substrates. Previously, this complex has been investigated in organic solvents tha
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9fa28ec9ff8b00d2aa5076736eca2207
https://doi.org/10.1002/ceat.201600684
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8
Copper Chloride Catalysis: Do μ4-Oxido Copper Clusters Play a Significant Role?
Autor: Siegfried Schindler, Jonathan Becker, Maximilian Dürr, Ulrich Behrens, Ivana Ivanović-Burmazović, Sabine Becker, Christopher Gawlig, Andreas Miska
Publikováno v: Inorganic Chemistry. 55:3759-3766
Copper chloride catalysis is a well-established field in organic and inorganic chemistry. However, in most cases a detailed mechanistic understanding of the individual reaction steps and identification of reactive intermediates are still missing. The
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a7be347244ead74429a9ca702926dcf2
https://doi.org/10.1021/acs.inorgchem.5b02576
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10
Fluoride-Assisted Activation of Calcium Carbide: A Simple Method for the Ethynylation of Aldehydes and Ketones
Autor: Abolfazl Hosseini, Daniel Seidel, Peter R. Schreiner, Andreas Miska
Publikováno v: Organic Letters. 17:2808-2811
The fluoride-assisted ethynylation of ketones and aldehydes is described using commercially available calcium carbide with typically 5 mol % of TBAF·3H2O as the catalyst in DMSO. Activation of calcium carbide by fluoride is thought to generate an ac
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6f9905596eaf81856a9494e394a74958
https://doi.org/10.1021/acs.orglett.5b01219
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