Zobrazeno 1 - 10
of 71
pro vyhledávání: '"Andreas J. Illies"'
Publikováno v:
Journal of Electroanalytical Chemistry. 610:102-105
Electrochemistry combined with electrospray mass spectrometry has proven to be very effective for investigating electrochemical processes. Results of the electrochemical oxidation of CN − at platinum electrode in acetonitrile using the electrochemi
Publikováno v:
The Journal of Physical Chemistry B. 109:7821-7825
Results on the electrochemistry of I- and SCN- at gold and platinum electrodes using an electrochemical cell coupled to an electrospray mass spectrometer are reported. We demonstrate that our apparatus is capable of these very challenging electrochem
Publikováno v:
Journal of Solid State Chemistry. 177:1717-1722
A new uranyl antimonite, UO2Sb2O4 (1), has been prepared from the hydrothermal reaction of UO3 with Sb2O3 and KCl. The structure of 1 consists of neutral two-dimensional ∞2[UO2Sb2O4] layers. The U(VI) centers are ligated by two trans oxo ligands an
Autor:
Andreas J. Illies, Joseph E. King
Publikováno v:
The Journal of Physical Chemistry A. 108:3581-3585
The first known experimental studies of two-center three-electron bonding involving tellurium in the gas, liquid, or solid state are reported. Ions studied include: [(CH3)2Te∴Te(CH3)2]+, [(CH3)2Te∴Se(CH3)2]+, [(CH3)2Te∴S(CH3)2]+, and [(CH3)2Te
Autor:
Joseph E. King, Andreas J. Illies
Publikováno v:
International Journal of Mass Spectrometry. 228:429-437
We report the first known experimental gas-phase study of two-center three-electron bonding involving selenium. Ions studied include: [(CH3)2Se∴Se(CH3)2]+, [(CH3)2Se∴Se(CH3)2]+ and [(CH3)2Se∴ICH3]+. We investigated these ions using metastable a
Autor:
Catherine E. Talley, Philip M. Almond, Andreas J. Illies, Casey C. Raymond, Thomas E. Albrecht-Schmitt
Publikováno v:
Journal of Crystal Growth. 217:250-254
Single crystals as large as 2 mm of binary transition metal and uranium arsenides and antimonides can be grown from the reactions of titanium, chromium, zirconium, hafnium, tantalum, rhenium, or uranium with alkali metal arsenides and antimonides fro
Autor:
Andreas J. Illies, Linda S. Nichols
Publikováno v:
Journal of the American Chemical Society. 121:9176-9181
An experimental study of the ion/molecule association reactions in mixtures of methyl halide and dimethyl sulfide has been performed. MS/MS metastable and collision-induced dissociation experiments were performed on each [C3H9SX]•+ association prod
Autor:
Linda S. Nichols, Andreas J. Illies
Publikováno v:
International Journal of Mass Spectrometry. :413-424
An experimental and theoretical study of the ion/molecule association reactions of methyl halide radical cations with mixed methyl halides (X, Y = I, Br, Cl, F) has been carried out. MS/MS unimolecular and collision-induced dissociation experiments w
Autor:
Andreas J. Illies
Publikováno v:
The Journal of Physical Chemistry A. 102:8774-8778
Experimental gas-phase high-pressure equilibrium determinations of ΔHorxn and ΔSorxn for the reactions: c-C4H8S+ + c-C4H8S ⇌ [c-C4H8S∴c-SC4H8]+, c-C5H10S+ + c-SC4H8 ⇌ [c-C5H10S∴c-SC4H8]+ and c-C5H10S+ + c-SC5H10 ⇌ [c-C5H10S∴c-SC5H10]+ h
Publikováno v:
Journal of the American Chemical Society. 120:1538-1544
An experimental and computational study of ion−molecule association reactions of the methyl halides has been carried out. A two-center three-electron bonded species, [CH3X∴XCH3]•+, has been observed for I and Br. MS/MS metastable and collision-