Zobrazeno 1 - 10
of 38
pro vyhledávání: '"Andreas Berkefeld"'
Publikováno v:
Inorganics, Vol 7, Iss 4, p 42 (2019)
Bimetallic structures of the general type [M2(µ-S)2] are omnipresent in nature, for biological function [M2(µ-S)2] sites interconvert between electronically distinct, but isostructural, forms. Different from structure-function relationships, the cu
Externí odkaz:
https://doaj.org/article/84ca945cff584f2c8270463861313f96
Publikováno v:
Organometallics. 40:1163-1177
This work reports on complex chromophores of planar nickel(II) of the general formula [(κ3-N,N′,C/O)Ni–ER], which combines a κ2-N,N′-coordinate aromatic N-heterocycle with a pendant phenyl/phenol d...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::eac6cf6a102a7846c63e6e1e5fd9e655
https://doi.org/10.1021/acs.organomet.1c00121
https://doi.org/10.1021/acs.organomet.1c00121
Publikováno v:
Inorganic Chemistry. 59:17234-17243
Sulfur-bridged bimetallic 2M-2S type structures are essential cofactors that participate in biological long-range electron transport and metabolism. Metal-sulfur bond covalency is a decisive property for inner sphere (through-bond) type electron tran
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f1460614ee71631e53eba66744429619
https://doi.org/10.1021/acs.inorgchem.0c02467
https://doi.org/10.1021/acs.inorgchem.0c02467
Publikováno v:
The Journal of Organic Chemistry. 85:15183-15196
We disclose a nickel/Bronsted acid-catalyzed tandem process consisting of double bond isomerization of allyl ethers and amines and subsequent intramolecular reaction with nucleophiles. The process is accomplished by [(Me3P)4NiH]N(SO2CF3)2 in the pres
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b64d1bd7be48765dd931b00dacd8cff0
https://doi.org/10.1021/acs.joc.0c02033
https://doi.org/10.1021/acs.joc.0c02033
Publikováno v:
Organometallics. 39:443-452
Transition-metal phosphanides M–PR2 are key intermediates in catalytic C–P bond functionalization. M–PR2 formation from tertiary phosphines through P–C bond cleavage widens the scope beyond P–H fun...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0b4738bd1d12503c2eaabff47663d179
https://doi.org/10.1021/acs.organomet.9b00807
https://doi.org/10.1021/acs.organomet.9b00807
Publikováno v:
Chemical Communications. 56:3987-3990
The selective C-metalation of phenol ester derived proligands is a readily applicable addition to state-of-the-art protocols toward cyclometalated structures, in particular of the base metals. The approach is demonstrated by the ortho-nickelation of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8e121b84c6b3320ec3273d68098d301b
https://doi.org/10.1039/d0cc01254h
https://doi.org/10.1039/d0cc01254h
Autor:
Wolfgang Leis, Miguel A. Argüello Cordero, Stefan Lochbrunner, Hartmut Schubert, Andreas Berkefeld
Publikováno v:
Journal of the American Chemical Society. 144(3)
Controlling the order and lifetimes of electronically excited states is essential to effective light-to-potential energy conversion by molecular chromophores. This work reports a luminescent and photoreactive iron(II) complex, the first performant gr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d319bd049b308c72c3970de38a4de3b8
https://pubmed.ncbi.nlm.nih.gov/35025493
https://pubmed.ncbi.nlm.nih.gov/35025493
Publikováno v:
Chemical Science
Homoleptic cerous complexes Ce[N(SiMe3)2]3, [Ce{OSi(OtBu)3}3]2 and [Ce{OSiiPr3}3]2 were employed as thermally robust, weakly nucleophilic precursors to assess their reactivity towards 1,4-quinones in non-aqueous solution. The strongly oxidizing quino
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f35fd22ee43006c4e6a44e37b209876e
https://pubmed.ncbi.nlm.nih.gov/34163897
https://pubmed.ncbi.nlm.nih.gov/34163897
Autor:
Hartmut Schubert, Martin Kaupp, Nicole M. Mews, Marc Reimann, Andreas Berkefeld, Gerald Hörner
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 49(28)
A system of four principal parameters is reported that provides a unified description of the electronic and chemical properties of radical-ligand coordination compounds. This type of parametrisation applies to compositionally different types of radic
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c17320fe6b83c076404250010a3f942d
https://pubmed.ncbi.nlm.nih.gov/32617540
https://pubmed.ncbi.nlm.nih.gov/32617540
Publikováno v:
Nachrichten aus der Chemie. 66:230-239
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7e37118af8ca7c56774882f5eddd3b11
https://doi.org/10.1002/nadc.20184071717
https://doi.org/10.1002/nadc.20184071717