Zobrazeno 1 - 10
of 178
pro vyhledávání: '"Andreas, Gansäuer"'
Autor:
Sebastian Höthker, Andreas Gansäuer
Publikováno v:
Global Challenges, Vol 7, Iss 7, Pp n/a-n/a (2023)
Abstract Here, the evolution of the titanocene‐catalyzed hydrosilylation of epoxides that yields the corresponding anti‐Markovnikov alcohols is summarized. The study focuses on aspects of sustainability, efficient catalyst activation, and stereos
Externí odkaz:
https://doaj.org/article/33a40fe7c354497b8b3847c2174a9d5f
Publikováno v:
Chemistry – A European Journal.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::94594ed74a9dd4a45b3dba658d1efa9c
https://doi.org/10.1002/chem.202301031
https://doi.org/10.1002/chem.202301031
Publikováno v:
The Journal of Physical Chemistry B. 126:766-777
The theoretical treatment of ionic liquids must focus now on more realistic models while at the same time keeping an accurate methodology when following recent ionic liquids research trends or allowing predictability to come to the foreground. In thi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a97e8577c38606b5824f7a28712d5272
https://doi.org/10.1021/acs.jpcb.1c09092
https://doi.org/10.1021/acs.jpcb.1c09092
Autor:
Jonathan Heinrich Schacht, Shangze Wu, Sven Klare, Sebastian Höthker, Niklas Schmickler, Andreas Gansäuer
Publikováno v:
ChemCatChem. 14
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::00855f356e96477cfc50f2bc43b90c1c
https://doi.org/10.1002/cctc.202201124
https://doi.org/10.1002/cctc.202201124
Autor:
Jonathan Heinrich Schacht, Shangze Wu, Sven Klare, Sebastian Höthker, Niklas Schmickler, Andreas Gansäuer
Publikováno v:
ChemCatChem. 14
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f49c5640d2032c33bc567209e7774b88
https://doi.org/10.1002/cctc.202200852
https://doi.org/10.1002/cctc.202200852
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 10, Iss 1, Pp 1630-1637 (2014)
An operationally simple, convenient, and mild strategy for the synthesis of triazole-substituted titanocenes via strain-driven 1,3-dipolar cycloadditions between azide-functionalized titanocenes and cyclooctyne has been developed. It features the fir
Externí odkaz:
https://doaj.org/article/4145ecbd99d4490a94d1e51ea5472cb6
Publikováno v:
Angewandte Chemie (International Ed. in English)
Cp2Ti(TFA) is a broadly applicable catalyst for the [2+2] cycloaddition of bisenones by inner‐sphere electron transfer. The attractiveness of this mechanism is shown by comparison with outer‐sphere ET methods. DFT calculations show that the react
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1841df3a81e618aedbd466a4e19e9704
https://doi.org/10.1002/anie.202102739
https://doi.org/10.1002/anie.202102739
Publikováno v:
ChemCatChem. 14
Low-valent titanocene catalysts are a versatile tool for organic synthesis. They promote inter- and intramolecular reactions ranging from homolytic bond cleavages to reductive umpolung reactions to additions and cyclizations in single electron steps.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fc1be08cbe6ce108f3d5696d646bcc43
https://doi.org/10.1002/cctc.202200530
https://doi.org/10.1002/cctc.202200530
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 9, Iss 1, Pp 1620-1629 (2013)
The intramolecular radical addition to aniline derivatives was investigated by DFT calculations. The computational methods were benchmarked by comparing the calculated values of the rate constant for the 5-exo cyclization of the hexenyl radical with
Externí odkaz:
https://doaj.org/article/2e7d3ee373c345bc8cbab2d618be00d0
Publikováno v:
Angewandte Chemie (International Ed. in English)
Described here is a titanocene‐catalyzed reaction for the synthesis of acetals and hemiaminals from benzylic ethers and benzylic amines, respectively, with pendant epoxides. The reaction proceeds by catalysis in single‐electron steps. The oxidati
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5e636672a896dfedf64ab8318b387b79
https://doi.org/10.1002/anie.202013561
https://doi.org/10.1002/anie.202013561