Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Andrea Schisler"'
Publikováno v:
Chemistry - A European Journal. 13:7974-7982
Na[cyclo-(P(5)tBu(4))] (1) reacts with [NiCl(2)(PEt(3))(2)] and [PdCl(2)(PMe(2)Ph)(2)] with elimination of tBuCl and formation of the corresponding metal(0) cyclopentaphosphene complexes [Ni{cyclo-(P(5)tBu(3))}(PEt(3))(2)] (2) and [Pd{cyclo-(P(5)tBu(
Publikováno v:
European Journal of Inorganic Chemistry. 2004:3277-3286
The reaction of sodium with RPCl2 and PCl3 (12:4:1) in THF gives Na[cyclo-(P5R4)] [R = iPr (1), Ph (2)], while four equivalents of RPCl2 [R = Ph, 2,4,6-Me3C6H2 (Mes), tBu] react with ten equivalents of sodium sand or elemental potassium in refluxing
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 177:1447-1450
The reaction between Na, t BuPCl 2 , and PCl 3 in thf gives Na[ cyclo -( t Bu 4 P 5 )] ( 1 ). 1 reacts with PCl 3 to yield ( cyclo - t Bu 3 P 4 ) t BuPCl ( 2 ), and with a proton source, such as HCl, NH 4 Cl, or t BuCl, to give cyclo - t Bu 4 P 5 H (
Publikováno v:
Angewandte Chemie. 113:4345-4348
Autor:
Henry Bittig, Santiago Gómez-Ruiz, Sebastian Bauer, Peter Lönnecke, Andrea Schisler, Robert Wolf, Evamarie Hey-Hawkins
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 14(15)
[Na{cyclo-(P(5)tBu(4))}] (1) reacts with [CuCl(PCyp(3))(2)] (Cyp=cyclo-C(5)H(9)) and [CuCl(PPh(3))(3)] (1:1) to give the corresponding copper(I) complexes with a tetra-tert-butylcyclopentaphosphanide ligand, [Cu{cyclo- (P(5)tBu(4))}(PCyp(3))(2)] (2)
Publikováno v:
Inorganic chemistry. 44(2)
Na[cyclo-(P(5)(t)Bu(4))] (1) reacts with [RhCl(PPh(3))(3)] (1:1) to give the first rhodium(I) complex with a tetra-tert-butylcyclopentaphosphanide ligand, [Rh{cyclo-(P(5)(t)Bu(4))}(PPh(3))(2)] (2). 2 was characterized by NMR ((1)H, (13)C, (31)P), MS,
Publikováno v:
Dalton Transactions. :2895
[Na(THF)4][cyclo-(P5tBu4)] (1) reacts with Et2AlCl and GeCl4 to give Et2Al{cyclo-(P5tBu4)}(THF) (2) and, in low yield, GeCl3{cyclo-(P5tBu4)}, respectively, while the reaction of 1 with SnCl2, PbCl2 or BiCl3 results in the formation of the structural
Publikováno v:
Dalton Transactions: An International Journal of Inorganic Chemistry; Sep2004, Vol. 2004 Issue 18, p2895-2898, 4p