Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Andrea Raselli"'
Publikováno v:
Helvetica Chimica Acta. 79:1607-1610
The molecular structure of the two complex ions [Co(tmen)3]3+ and [Co(tmen)3]2+ (tmen = 2,3-dimethylbutane-2,3-diamine) have been determined at 100 K. They show a strong trigonal distortion of the octahedral CoN6 core. The twist angle is 26.2(2.8)°
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::59274ed4bcb4d04297fa0e3292ad0a7e
https://doi.org/10.1002/hlca.19960790610
https://doi.org/10.1002/hlca.19960790610
Autor:
Andrea Raselli, H.-B. Bürgi
Publikováno v:
Structural Chemistry. 4:23-31
Atomic displacement parameters determined from a single-crystal X-ray-diffraction study on K2Ru(SO4)2 * 6H2O are analyzed in the molecular mean field approximation. The motion of SO22− can be described with a rigid-body model, whereas for [Ru(H2O)6
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::baa83f2f9d3f9713ffe732b7238204ab
https://doi.org/10.1007/bf00672096
https://doi.org/10.1007/bf00672096
Publikováno v:
Inorganic Chemistry. 31:4766-4773
The crystal structure of [Rh(phpy) 2 (bpy)] PF 6 (phpyH=2-phenylpyridine, bpy=2,2'-bipyridine) is determined and described. Crystallographic data at 100 K: chemical formula C 32 H 24 F 6 N 4 PRh, orthorhombic crystal system, space group Pbca (No. 61)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0ac470981dce6a51631c7998785df1a6
https://doi.org/10.1021/ic00049a011
https://doi.org/10.1021/ic00049a011
Publikováno v:
Inorganic Chemistry. 31:3405-3410
(NH 4 ) 2 OsBr 6 reacts smoothly with an excess of 2,3-diamino-2,3-dimethylbutane (tmen) in water to give a brown Os(IV) tris-chelate complex which has lost two protons from two different ligands, [Os(tmen-H) 2 tmen] 2+ . In 6 M trifluoromethanesulfo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b0e5e1010db0a8feb8b8619320ad8eb1
https://doi.org/10.1021/ic00042a015
https://doi.org/10.1021/ic00042a015
Autor:
Andrea Raselli, Hans-Beat Bürgi, Peter Osvath, Alan M. Sargeson, Paul Bernhard, Daryl J. Bull
Publikováno v:
Inorganic chemistry. 36(13)
The mechanisms of oxidative ligand dehydrogenation in high-valent ruthenium hexaamine complexes of bidentate 1,2-ethanediamine (en) and tridentate 1,1,1-tris(aminomethyl)ethane (tame) are elucidated in detail. In basic aqueous solution, [Ru(III)(tame
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bd7e825b66bd4d9b144389e4d57b0cf5
https://pubmed.ncbi.nlm.nih.gov/11669915
https://pubmed.ncbi.nlm.nih.gov/11669915
Publikováno v:
Inorganic Chemistry. 28:3234-3239
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5fcce69c2b8d7c5a9a2a97db64c0d349
https://doi.org/10.1021/ic00315a031
https://doi.org/10.1021/ic00315a031
The crystal and molecular structures of two vitamin B12 models containing anisidine as neutral ligand, anisidineCo(DH)2alkyl, where (DH)=monoanion of dimethylglyoxime and alkyl=methyl (1), i-propyl (2) are reported. The compounds are isomorphous and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f8c12fc972d306bc5caf38e1e81e15d7
http://hdl.handle.net/11368/2296054
http://hdl.handle.net/11368/2296054
